Forced peptide synthesis in nanoscale confinement under elastomeric stamps

T.P. Sullivan; M.L. Poll, van; P.Y.W. Dankers; W.T.S. Huck

doi:10.1002/anie.200460271

Forced peptide synthesis in nanoscale confinement under elastomeric stamps

T.P. Sullivan, M.L. Poll, van, P.Y.W. Dankers, W.T.S. Huck

Research output: Contribution to journal › Article › Academic › peer-review

49 Citations (Scopus)

Abstract

Pressing a rubber stamp inked with carboxylic acids onto an amine-terminated surface leads to the formation of amide bonds at room temperature (see scheme). Oligopeptides were created on the surface in this way from a monolayer. This rapid and uncatalyzed formation of amide bonds is attributed to the nanoscale confinement of the molecules between the stamp and the preorganized monolayer substrate. PDMS=poly(dimethylsiloxane).

Original language	English
Pages (from-to)	4190-4193
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	32
DOIs	https://doi.org/10.1002/anie.200460271
Publication status	Published - 2004

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abstract = "Pressing a rubber stamp inked with carboxylic acids onto an amine-terminated surface leads to the formation of amide bonds at room temperature (see scheme). Oligopeptides were created on the surface in this way from a monolayer. This rapid and uncatalyzed formation of amide bonds is attributed to the nanoscale confinement of the molecules between the stamp and the preorganized monolayer substrate. PDMS=poly(dimethylsiloxane).",

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AU - Poll, van, M.L.

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AU - Huck, W.T.S.

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AB - Pressing a rubber stamp inked with carboxylic acids onto an amine-terminated surface leads to the formation of amide bonds at room temperature (see scheme). Oligopeptides were created on the surface in this way from a monolayer. This rapid and uncatalyzed formation of amide bonds is attributed to the nanoscale confinement of the molecules between the stamp and the preorganized monolayer substrate. PDMS=poly(dimethylsiloxane).

U2 - 10.1002/anie.200460271

DO - 10.1002/anie.200460271

M3 - Article

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VL - 43

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JO - Angewandte Chemie - International Edition

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