Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands

B. Hamers; E. Kosciusko-Morizet; C. Müller; D. Vogt

doi:10.1002/cctc.200900088

Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands

B. Hamers, E. Kosciusko-Morizet, C. Müller, D. Vogt

Catalysis and Organometallic Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Hydroaminomethylation of 1-octene and piperidine has been carried out using a pyrrole-substituted phosphine ligand (see Scheme; L), giving extremely high activities (TOF6200 h-1) and selectivities (linear/branched ratios>200). Acidic alcohols in the solvent mixture lead to higher activities but lower selectivities, whereas less acidic alcohols give extraordinarily good selectivities.

Original language	English
Pages (from-to)	103-106
Journal	ChemCatChem
Volume	1
Issue number	1
DOIs	https://doi.org/10.1002/cctc.200900088
Publication status	Published - 2009

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Hamers, B., Kosciusko-Morizet, E., Müller, C., & Vogt, D. (2009). Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands. ChemCatChem, 1(1), 103-106. https://doi.org/10.1002/cctc.200900088

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