Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands

B. Hamers, E. Kosciusko-Morizet, C. Müller, D. Vogt

    Research output: Contribution to journalArticleAcademicpeer-review

    47 Citations (Scopus)
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    Abstract

    Hydroaminomethylation of 1-octene and piperidine has been carried out using a pyrrole-substituted phosphine ligand (see Scheme; L), giving extremely high activities (TOF6200 h-1) and selectivities (linear/branched ratios>200). Acidic alcohols in the solvent mixture lead to higher activities but lower selectivities, whereas less acidic alcohols give extraordinarily good selectivities.
    Original languageEnglish
    Pages (from-to)103-106
    JournalChemCatChem
    Volume1
    Issue number1
    DOIs
    Publication statusPublished - 2009

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