Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands

B. Hamers; E. Kosciusko-Morizet; C. Müller; D. Vogt

doi:10.1002/cctc.200900088

Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands

B. Hamers, E. Kosciusko-Morizet, C. Müller, D. Vogt

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Abstract

Hydroaminomethylation of 1-octene and piperidine has been carried out using a pyrrole-substituted phosphine ligand (see Scheme; L), giving extremely high activities (TOF6200 h-1) and selectivities (linear/branched ratios>200). Acidic alcohols in the solvent mixture lead to higher activities but lower selectivities, whereas less acidic alcohols give extraordinarily good selectivities.

Original language	English
Pages (from-to)	103-106
Journal	ChemCatChem
Volume	1
Issue number	1
DOIs	https://doi.org/10.1002/cctc.200900088
Publication status	Published - 2009

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title = "Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands",

abstract = "Hydroaminomethylation of 1-octene and piperidine has been carried out using a pyrrole-substituted phosphine ligand (see Scheme; L), giving extremely high activities (TOF6200 h-1) and selectivities (linear/branched ratios>200). Acidic alcohols in the solvent mixture lead to higher activities but lower selectivities, whereas less acidic alcohols give extraordinarily good selectivities.",

author = "B. Hamers and E. Kosciusko-Morizet and C. M{\"u}ller and D. Vogt",

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AU - Kosciusko-Morizet, E.

AU - Müller, C.

AU - Vogt, D.

PY - 2009

Y1 - 2009

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AB - Hydroaminomethylation of 1-octene and piperidine has been carried out using a pyrrole-substituted phosphine ligand (see Scheme; L), giving extremely high activities (TOF6200 h-1) and selectivities (linear/branched ratios>200). Acidic alcohols in the solvent mixture lead to higher activities but lower selectivities, whereas less acidic alcohols give extraordinarily good selectivities.

U2 - 10.1002/cctc.200900088

DO - 10.1002/cctc.200900088

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EP - 106

JO - ChemCatChem

JF - ChemCatChem

SN - 1867-3880

IS - 1

ER -

Fast and selective hydroaminomethylation using xanthene-based amino-functionalized ligands

Abstract

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