Extraction of sodium chloride from water and solubility of water in hydrophobic trialkylammonium alkanoate-based ionic liquids

C.H.C. Janssen, M.C. Kroon, S.J. Metz, J. Spronsen, van, G.J. Witkamp

    Research output: Contribution to journalArticleAcademicpeer-review

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    Abstract

    The sodium chloride extraction from aqueous solutions by using hydrophobic trialkylammonium alkanoate ionic liquids (ILs) is studied experimentally. The water solubility in these ILs is also determined. It is found that trialkylammonium alkanoate ILs show sodium chloride extraction efficiencies up to 0.101 g NaCl extracted/g NaCl start. This efficiency cannot be explained by the low water uptake (up to 0.02 gwater/gIL) in the IL. Instead, the sodium chloride extraction must be attributed to other factors, such as steric hindrance considerations. Steric hindrance considerations also explain the dependence of sodium chloride extraction efficiency on the IL structure. Kinetic experiments were performed to ensure a state of chemical equilibrium
    Original languageEnglish
    Pages (from-to)3391-3394
    JournalJournal of Chemical and Engineering Data
    Volume55
    Issue number9
    DOIs
    Publication statusPublished - 2010

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    Ionic Liquids
    Sodium chloride
    Ionic liquids
    Sodium Chloride
    Solubility
    Water
    Kinetics
    Experiments

    Cite this

    Janssen, C.H.C. ; Kroon, M.C. ; Metz, S.J. ; Spronsen, van, J. ; Witkamp, G.J. / Extraction of sodium chloride from water and solubility of water in hydrophobic trialkylammonium alkanoate-based ionic liquids. In: Journal of Chemical and Engineering Data. 2010 ; Vol. 55, No. 9. pp. 3391-3394.
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    abstract = "The sodium chloride extraction from aqueous solutions by using hydrophobic trialkylammonium alkanoate ionic liquids (ILs) is studied experimentally. The water solubility in these ILs is also determined. It is found that trialkylammonium alkanoate ILs show sodium chloride extraction efficiencies up to 0.101 g NaCl extracted/g NaCl start. This efficiency cannot be explained by the low water uptake (up to 0.02 gwater/gIL) in the IL. Instead, the sodium chloride extraction must be attributed to other factors, such as steric hindrance considerations. Steric hindrance considerations also explain the dependence of sodium chloride extraction efficiency on the IL structure. Kinetic experiments were performed to ensure a state of chemical equilibrium",
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    Extraction of sodium chloride from water and solubility of water in hydrophobic trialkylammonium alkanoate-based ionic liquids. / Janssen, C.H.C.; Kroon, M.C.; Metz, S.J.; Spronsen, van, J.; Witkamp, G.J.

    In: Journal of Chemical and Engineering Data, Vol. 55, No. 9, 2010, p. 3391-3394.

    Research output: Contribution to journalArticleAcademicpeer-review

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    AU - Janssen, C.H.C.

    AU - Kroon, M.C.

    AU - Metz, S.J.

    AU - Spronsen, van, J.

    AU - Witkamp, G.J.

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    N2 - The sodium chloride extraction from aqueous solutions by using hydrophobic trialkylammonium alkanoate ionic liquids (ILs) is studied experimentally. The water solubility in these ILs is also determined. It is found that trialkylammonium alkanoate ILs show sodium chloride extraction efficiencies up to 0.101 g NaCl extracted/g NaCl start. This efficiency cannot be explained by the low water uptake (up to 0.02 gwater/gIL) in the IL. Instead, the sodium chloride extraction must be attributed to other factors, such as steric hindrance considerations. Steric hindrance considerations also explain the dependence of sodium chloride extraction efficiency on the IL structure. Kinetic experiments were performed to ensure a state of chemical equilibrium

    AB - The sodium chloride extraction from aqueous solutions by using hydrophobic trialkylammonium alkanoate ionic liquids (ILs) is studied experimentally. The water solubility in these ILs is also determined. It is found that trialkylammonium alkanoate ILs show sodium chloride extraction efficiencies up to 0.101 g NaCl extracted/g NaCl start. This efficiency cannot be explained by the low water uptake (up to 0.02 gwater/gIL) in the IL. Instead, the sodium chloride extraction must be attributed to other factors, such as steric hindrance considerations. Steric hindrance considerations also explain the dependence of sodium chloride extraction efficiency on the IL structure. Kinetic experiments were performed to ensure a state of chemical equilibrium

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