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External RF substrate biasing as a tool to improve the material properties of hydrogenated amorphous silicon at high deposition rates by means of the expanding thermal plasma

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Abstract

An external rf substrate bias (ERFSB) has been employed during the deposition of hydrogenated amorphous silicon (a-Si:H) by means of the expanding thermal plasma (ETP) deposition technique. The effects of the additional created ion bombardment on the a-Si:H material properties, such as the microstructure and defects, have been studied. The incorporation of nano-sized voids is reduced under ERFSB whereas the incorporation of vacancies is enhanced. The mass density increases with increasing rf power (Prf). For moderate ERFSB (Prf>12 W) the sub gap absorption of the a-Si:H material is reduced drastically. Possible plasma and ion bombardment induced surface processes responsible for these observations are discussed. Finally, it is demonstrated that the performance of the pin cells with a-Si:H films deposited with ERFSB improves.
Original languageEnglish
Title of host publicationProceedings of the 31st Conference Record on Photovoltaic Specialists, 3-7 January 2005, Coronado Springs Resort, Lake Buena Vista, FL,USA
Pages1389-1392
Publication statusPublished - 2005
Event31st IEEE Photovoltaic Specialists Conference (PVSC 2005) - Coronado Springs Resort, Lake Buena Vista, United States
Duration: 3 Jan 20057 Jan 2005
Conference number: 31

Conference

Conference31st IEEE Photovoltaic Specialists Conference (PVSC 2005)
Abbreviated titlePVSC 2005
Country/TerritoryUnited States
CityLake Buena Vista
Period3/01/057/01/05

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