Experimental densities, dynamic viscosities and surface tensions of the ionic liquids series 1-ethyl-3-methylimidazolium acetate and dicyanamide and their binary and ternary mixtures with water and ethanol at T = (298.15 to 343.15 K)

E. Quijada-Maldonado, S. Boogaart, van der, J.H. Lijbers, G.W. Meindersma, A.B. Haan, de

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    Abstract

    In this paper, experimental densities and dynamic viscosities of 1-ethyl-3-methylimidazolium based ionic liquids (ILs) with the anions acetate and dicyanamide are presented in a wide temperature range (298.15 to 343.15 K) at atmospheric pressure. Surface tension of these ILs was measured at T = 298.15 K. The effect of water and/or ethanol compositions on densities and dynamic viscosities of these ILs are studied in binary and ternary mixtures. A quadratic mixing rule was used to correlate binary and ternary liquid densities. The Eyring–Patel–Teja model, which is recommended for polar and aqueous systems, is used to correlate dynamic viscosity data over the whole range of compositions and temperatures in binary and ternary mixtures. Temperature-dependent interaction parameters are introduced here to account for the changes of viscosities with temperature showing good agreements with experimental data.
    Original languageEnglish
    Pages (from-to)51-58
    Number of pages8
    JournalThe Journal of Chemical Thermodynamics
    Volume51
    DOIs
    Publication statusPublished - 2012

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