TY - JOUR
T1 - Evidence of prevailing strain effects on the valence state of the 5-phenyl-4,6-dioxa-1-aza-5-phospha(V)bicyclo[3.3.0]octan-5-yl radical
AU - Hamerlinck, J.H.H.
AU - Schipper, P.
AU - Buck, H.M.
PY - 1979
Y1 - 1979
N2 - The valence state of phenylphosphoranyl radicals, which has been shown to depend on the electro-negativity of the other ligands, appears also to be influenced by incorportion of the phosphorus within a rigid skeleton, which forces the unpaired electron of the bicyclic title compound to be centred on phosphorus in contrast to the behaviour of its acyclic analogue, in which the unpaired electron is preferentially located on the aromatic ring.
AB - The valence state of phenylphosphoranyl radicals, which has been shown to depend on the electro-negativity of the other ligands, appears also to be influenced by incorportion of the phosphorus within a rigid skeleton, which forces the unpaired electron of the bicyclic title compound to be centred on phosphorus in contrast to the behaviour of its acyclic analogue, in which the unpaired electron is preferentially located on the aromatic ring.
U2 - 10.1039/C39790000350
DO - 10.1039/C39790000350
M3 - Article
SN - 0022-4936
SP - 350
EP - 351
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 7
ER -