Evidence for termination of intermediate radical species in RAFT-mediated polymerization

F.M. Calitz; J.B. McLeary; J.M. McKenzie; M.P. Tonge; B. Klumperman; R.D. Sanderson

doi:10.1021/ma0353787

Evidence for termination of intermediate radical species in RAFT-mediated polymerization

F.M. Calitz, J.B. McLeary, J.M. McKenzie, M.P. Tonge, B. Klumperman, R.D. Sanderson

Department of Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

66 Citations (Scopus)

Abstract

The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conversion, and high radical concns. were present. The main reasons why species resulting from termination of intermediate radicals were given.

Original language	English
Pages (from-to)	9687-9690
Journal	Macromolecules
Volume	36
Issue number	26
DOIs	https://doi.org/10.1021/ma0353787
Publication status	Published - 2003

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title = "Evidence for termination of intermediate radical species in RAFT-mediated polymerization",

abstract = "The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conversion, and high radical concns. were present. The main reasons why species resulting from termination of intermediate radicals were given.",

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AU - Calitz, F.M.

AU - McLeary, J.B.

AU - McKenzie, J.M.

AU - Tonge, M.P.

AU - Klumperman, B.

AU - Sanderson, R.D.

PY - 2003

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AB - The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conversion, and high radical concns. were present. The main reasons why species resulting from termination of intermediate radicals were given.

U2 - 10.1021/ma0353787

DO - 10.1021/ma0353787

M3 - Article

VL - 36

SP - 9687

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JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 26

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