Evidence for termination of intermediate radical species in RAFT-mediated polymerization

F.M. Calitz, J.B. McLeary, J.M. McKenzie, M.P. Tonge, B. Klumperman, R.D. Sanderson

Research output: Contribution to journalArticleAcademicpeer-review

66 Citations (Scopus)

Abstract

The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conversion, and high radical concns. were present. The main reasons why species resulting from termination of intermediate radicals were given.
Original languageEnglish
Pages (from-to)9687-9690
JournalMacromolecules
Volume36
Issue number26
DOIs
Publication statusPublished - 2003

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