Evidence for termination of intermediate radical species in RAFT-mediated polymerization

F.M. Calitz, J.B. McLeary, J.M. McKenzie, M.P. Tonge, B. Klumperman, R.D. Sanderson

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Abstract

The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conversion, and high radical concns. were present. The main reasons why species resulting from termination of intermediate radicals were given.
Original languageEnglish
Pages (from-to)9687-9690
JournalMacromolecules
Volume36
Issue number26
DOIs
Publication statusPublished - 2003

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Styrene
Polymerization
cumyl dithiobenzoate

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Calitz, F. M., McLeary, J. B., McKenzie, J. M., Tonge, M. P., Klumperman, B., & Sanderson, R. D. (2003). Evidence for termination of intermediate radical species in RAFT-mediated polymerization. Macromolecules, 36(26), 9687-9690. https://doi.org/10.1021/ma0353787
Calitz, F.M. ; McLeary, J.B. ; McKenzie, J.M. ; Tonge, M.P. ; Klumperman, B. ; Sanderson, R.D. / Evidence for termination of intermediate radical species in RAFT-mediated polymerization. In: Macromolecules. 2003 ; Vol. 36, No. 26. pp. 9687-9690.
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Calitz, FM, McLeary, JB, McKenzie, JM, Tonge, MP, Klumperman, B & Sanderson, RD 2003, 'Evidence for termination of intermediate radical species in RAFT-mediated polymerization', Macromolecules, vol. 36, no. 26, pp. 9687-9690. https://doi.org/10.1021/ma0353787

Evidence for termination of intermediate radical species in RAFT-mediated polymerization. / Calitz, F.M.; McLeary, J.B.; McKenzie, J.M.; Tonge, M.P.; Klumperman, B.; Sanderson, R.D.

In: Macromolecules, Vol. 36, No. 26, 2003, p. 9687-9690.

Research output: Contribution to journalArticleAcademicpeer-review

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T1 - Evidence for termination of intermediate radical species in RAFT-mediated polymerization

AU - Calitz, F.M.

AU - McLeary, J.B.

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AU - Tonge, M.P.

AU - Klumperman, B.

AU - Sanderson, R.D.

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AB - The reactions of short-chain species during the initial periods of cumyl dithiobenzoate (CDB)-mediated polymns. of styrene were studied at 84 Deg. High initiator and CDB concns. were chosen such that very short chains were targeted at complete conversion, and high radical concns. were present. The main reasons why species resulting from termination of intermediate radicals were given.

U2 - 10.1021/ma0353787

DO - 10.1021/ma0353787

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JO - Macromolecules

JF - Macromolecules

SN - 0024-9297

IS - 26

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Calitz FM, McLeary JB, McKenzie JM, Tonge MP, Klumperman B, Sanderson RD. Evidence for termination of intermediate radical species in RAFT-mediated polymerization. Macromolecules. 2003;36(26):9687-9690. https://doi.org/10.1021/ma0353787