Evaporation induced micellization of poly(2-oxazoline) multiblock copolymers on surfaces

C.A. Fustin; H. Huang; R. Hoogenboom; F.D. Wiesbrock; A.M. Jonas; U.S. Schubert; J.M.W. Gohy

doi:10.1039/b611962j

Evaporation induced micellization of poly(2-oxazoline) multiblock copolymers on surfaces

C.A. Fustin, H. Huang, R. Hoogenboom, F.D. Wiesbrock, A.M. Jonas, U.S. Schubert, J.M.W. Gohy

Department of Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

13 Citations (Scopus)

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Abstract

The formation of micelles on surfaces by spin-coating dilute solutions of diblock, triblock, and tetrablock copoly(2-oxazoline)s in a non-selective solvent is demonstrated. The micelles are not preexistent in the initial solution but are formed during the evaporation of the solvent by precipitation of the least-soluble block. The morphology and size of the micelles vary according to the fraction of this block but are not dependent on the block order in the copolymer.

Original language	English
Pages (from-to)	79-82
Journal	Soft Matter
Volume	3
Issue number	1
DOIs	https://doi.org/10.1039/b611962j
Publication status	Published - 2007

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title = "Evaporation induced micellization of poly(2-oxazoline) multiblock copolymers on surfaces",

abstract = "The formation of micelles on surfaces by spin-coating dilute solutions of diblock, triblock, and tetrablock copoly(2-oxazoline)s in a non-selective solvent is demonstrated. The micelles are not preexistent in the initial solution but are formed during the evaporation of the solvent by precipitation of the least-soluble block. The morphology and size of the micelles vary according to the fraction of this block but are not dependent on the block order in the copolymer.",

author = "C.A. Fustin and H. Huang and R. Hoogenboom and F.D. Wiesbrock and A.M. Jonas and U.S. Schubert and J.M.W. Gohy",

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journal = "Soft Matter",

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T1 - Evaporation induced micellization of poly(2-oxazoline) multiblock copolymers on surfaces

AU - Fustin, C.A.

AU - Huang, H.

AU - Hoogenboom, R.

AU - Wiesbrock, F.D.

AU - Jonas, A.M.

AU - Schubert, U.S.

AU - Gohy, J.M.W.

PY - 2007

Y1 - 2007

N2 - The formation of micelles on surfaces by spin-coating dilute solutions of diblock, triblock, and tetrablock copoly(2-oxazoline)s in a non-selective solvent is demonstrated. The micelles are not preexistent in the initial solution but are formed during the evaporation of the solvent by precipitation of the least-soluble block. The morphology and size of the micelles vary according to the fraction of this block but are not dependent on the block order in the copolymer.

AB - The formation of micelles on surfaces by spin-coating dilute solutions of diblock, triblock, and tetrablock copoly(2-oxazoline)s in a non-selective solvent is demonstrated. The micelles are not preexistent in the initial solution but are formed during the evaporation of the solvent by precipitation of the least-soluble block. The morphology and size of the micelles vary according to the fraction of this block but are not dependent on the block order in the copolymer.

U2 - 10.1039/b611962j

DO - 10.1039/b611962j

M3 - Article

VL - 3

SP - 79

EP - 82

JO - Soft Matter

JF - Soft Matter

SN - 1744-683X

IS - 1

ER -