Equal reactivity of amide groups in acid hydrolysis of polyamides from e-aminocaproic acid

D. Heikens

doi:10.1002/pol.1956.1202210009

Equal reactivity of amide groups in acid hydrolysis of polyamides from e-aminocaproic acid

D. Heikens

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

Certain samples of the linear dimer and trimer and of a mixt. of linear oligomers of e-aminocaproic acid were hydrolyzed in aq. 7.72N HCl at 110 Deg for chosen time intervals. The rate constant pertaining to the hydrolysis of the amide groups is independent of chain length and has the value of 0.24/hr.; this proves that in this system the principle of equal reactivity holds. [on SciFinder (R)]

Original language	English
Pages (from-to)	65-70
Number of pages	6
Journal	Journal of Polymer Science
Volume	22
Issue number	100
DOIs	https://doi.org/10.1002/pol.1956.1202210009
Publication status	Published - 1956

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10.1002/pol.1956.1202210009

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@article{fffbee72271140f997715418d81024df,

title = "Equal reactivity of amide groups in acid hydrolysis of polyamides from e-aminocaproic acid",

abstract = "Certain samples of the linear dimer and trimer and of a mixt. of linear oligomers of e-aminocaproic acid were hydrolyzed in aq. 7.72N HCl at 110 Deg for chosen time intervals. The rate constant pertaining to the hydrolysis of the amide groups is independent of chain length and has the value of 0.24/hr.; this proves that in this system the principle of equal reactivity holds. [on SciFinder (R)]",

author = "D. Heikens",

year = "1956",

doi = "10.1002/pol.1956.1202210009",

language = "English",

volume = "22",

pages = "65--70",

journal = "Journal of Polymer Science",

issn = "0022-3832",

publisher = "Wiley-Interscience",

number = "100",

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TY - JOUR

T1 - Equal reactivity of amide groups in acid hydrolysis of polyamides from e-aminocaproic acid

AU - Heikens, D.

PY - 1956

Y1 - 1956

N2 - Certain samples of the linear dimer and trimer and of a mixt. of linear oligomers of e-aminocaproic acid were hydrolyzed in aq. 7.72N HCl at 110 Deg for chosen time intervals. The rate constant pertaining to the hydrolysis of the amide groups is independent of chain length and has the value of 0.24/hr.; this proves that in this system the principle of equal reactivity holds. [on SciFinder (R)]

AB - Certain samples of the linear dimer and trimer and of a mixt. of linear oligomers of e-aminocaproic acid were hydrolyzed in aq. 7.72N HCl at 110 Deg for chosen time intervals. The rate constant pertaining to the hydrolysis of the amide groups is independent of chain length and has the value of 0.24/hr.; this proves that in this system the principle of equal reactivity holds. [on SciFinder (R)]

U2 - 10.1002/pol.1956.1202210009

DO - 10.1002/pol.1956.1202210009

M3 - Article

SN - 0022-3832

VL - 22

SP - 65

EP - 70

JO - Journal of Polymer Science

JF - Journal of Polymer Science

IS - 100

ER -

Equal reactivity of amide groups in acid hydrolysis of polyamides from e-aminocaproic acid

Abstract

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