Enzymatic catalysis in the synthesis of poly(lactones-co-methacrylate) block copolymers

M. Geus, de; A.R.A. Palmans; C.E. Koning; A. Heise

Enzymatic catalysis in the synthesis of poly(lactones-co-methacrylate) block copolymers

M. Geus, de, A.R.A. Palmans, C.E. Koning, A. Heise

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

1The synthesis of block copolymers combining enzymic ring opening polymn. and ATRP in one pot employing a bifunctional initiator are described. Detailed investigations of the reaction conditions show the influence of water on the block copolymer yield. Moreover, the effect of ATRP catalysts systems strongly depends on the metal: no influence on the reaction kinetic of the enzymic reaction was obsd. for CuBr/PMDETA, whereas (PPh3)2NiBr2 reversible reduces the enzyme activity. [on SciFinder (R)]

Original language	English
Pages (from-to)	613-614
Journal	Polymer Preprints
Volume	44
Issue number	2
Publication status	Published - 2003

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title = "Enzymatic catalysis in the synthesis of poly(lactones-co-methacrylate) block copolymers",

abstract = "1The synthesis of block copolymers combining enzymic ring opening polymn. and ATRP in one pot employing a bifunctional initiator are described. Detailed investigations of the reaction conditions show the influence of water on the block copolymer yield. Moreover, the effect of ATRP catalysts systems strongly depends on the metal: no influence on the reaction kinetic of the enzymic reaction was obsd. for CuBr/PMDETA, whereas (PPh3)2NiBr2 reversible reduces the enzyme activity. [on SciFinder (R)]",

author = "{Geus, de}, M. and A.R.A. Palmans and C.E. Koning and A. Heise",

year = "2003",

language = "English",

volume = "44",

pages = "613--614",

journal = "Polymer Preprints",

issn = "0032-3934",

number = "2",

}

TY - JOUR

T1 - Enzymatic catalysis in the synthesis of poly(lactones-co-methacrylate) block copolymers

AU - Geus, de, M.

AU - Palmans, A.R.A.

AU - Koning, C.E.

AU - Heise, A.

PY - 2003

Y1 - 2003

N2 - 1The synthesis of block copolymers combining enzymic ring opening polymn. and ATRP in one pot employing a bifunctional initiator are described. Detailed investigations of the reaction conditions show the influence of water on the block copolymer yield. Moreover, the effect of ATRP catalysts systems strongly depends on the metal: no influence on the reaction kinetic of the enzymic reaction was obsd. for CuBr/PMDETA, whereas (PPh3)2NiBr2 reversible reduces the enzyme activity. [on SciFinder (R)]

AB - 1The synthesis of block copolymers combining enzymic ring opening polymn. and ATRP in one pot employing a bifunctional initiator are described. Detailed investigations of the reaction conditions show the influence of water on the block copolymer yield. Moreover, the effect of ATRP catalysts systems strongly depends on the metal: no influence on the reaction kinetic of the enzymic reaction was obsd. for CuBr/PMDETA, whereas (PPh3)2NiBr2 reversible reduces the enzyme activity. [on SciFinder (R)]

M3 - Article

SN - 0032-3934

VL - 44

SP - 613

EP - 614

JO - Polymer Preprints

JF - Polymer Preprints

IS - 2

ER -

Enzymatic catalysis in the synthesis of poly(lactones-co-methacrylate) block copolymers

Abstract

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