Entropic separations of mixtures of aromatics by selective face-to-face molecular stacking in one-dimensional channels of metal-organic frameworks and zeolites

Ariana Torres-Knoop; Salvador R.G. Balestra; Rajamani Krishna; Sofía Calero; David Dubbeldam

doi:10.1002/cphc.201402819

Entropic separations of mixtures of aromatics by selective face-to-face molecular stacking in one-dimensional channels of metal-organic frameworks and zeolites

Ariana Torres-Knoop, Salvador R.G. Balestra, Rajamani Krishna, Sofía Calero, David Dubbeldam

Research output: Contribution to journal › Article › Academic › peer-review

15 Citations (Scopus)

Abstract

Separation of challenging mixtures using metal-organic frameworks can be achieved by an entropy-driven mechanism, where one of the components can arrange into a "face-to-face" stacking, thus reducing its "footprint" and reaching a higher saturation loading.

Original language	English
Pages (from-to)	532-535
Number of pages	4
Journal	ChemPhysChem
Volume	16
Issue number	3
DOIs	https://doi.org/10.1002/cphc.201402819
Publication status	Published - 11 Dec 2015
Externally published	Yes

Keywords

Aromatic compounds
Entropy
Mixtures
MOFs
Separation

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10.1002/cphc.201402819

Cite this

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Entropic separations of mixtures of aromatics by selective face-to-face molecular stacking in one-dimensional channels of metal-organic frameworks and zeolites. / Torres-Knoop, Ariana; Balestra, Salvador R.G.; Krishna, Rajamani et al.

In: ChemPhysChem, Vol. 16, No. 3, 11.12.2015, p. 532-535.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Entropic separations of mixtures of aromatics by selective face-to-face molecular stacking in one-dimensional channels of metal-organic frameworks and zeolites

AU - Torres-Knoop, Ariana

AU - Balestra, Salvador R.G.

AU - Krishna, Rajamani

AU - Calero, Sofía

AU - Dubbeldam, David

PY - 2015/12/11

Y1 - 2015/12/11

N2 - Separation of challenging mixtures using metal-organic frameworks can be achieved by an entropy-driven mechanism, where one of the components can arrange into a "face-to-face" stacking, thus reducing its "footprint" and reaching a higher saturation loading.

AB - Separation of challenging mixtures using metal-organic frameworks can be achieved by an entropy-driven mechanism, where one of the components can arrange into a "face-to-face" stacking, thus reducing its "footprint" and reaching a higher saturation loading.

KW - Aromatic compounds

KW - Entropy

KW - Mixtures

KW - MOFs

KW - Separation

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DO - 10.1002/cphc.201402819

M3 - Article

AN - SCOPUS:85027934037

SN - 1439-4235

VL - 16

SP - 532

EP - 535

JO - ChemPhysChem

JF - ChemPhysChem

IS - 3

ER -

Entropic separations of mixtures of aromatics by selective face-to-face molecular stacking in one-dimensional channels of metal-organic frameworks and zeolites

Abstract

Keywords

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