Engineering with metallo-supramolecular polymers : linear coordination polymers and networks

S. Schmatloch, U.S. Schubert

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

29 Citations (Scopus)
1 Downloads (Pure)

Abstract

Here we demonstrate the synthesis of telechelics with different spacer units and different numbers of metal-complexing units, like -methoxy--(2,2:6,2-terpyrid-4-yl)-poly(ethylenoxide)78 (1), bis(2,2:6,2-terpyrid-4-yl) di(ethylene glycol) (2), bis(2,2:6,2-terpyrid-4-yl)-poly(ethylene oxide)180 (3) and tris[(2,2:6,2-terpyrid-4-yl)-oligo (ethylenoxy-)3.33]glycerin (4) utilizing 4-chloro-2,2:6,2-terpyridine. The complexation behaviour of a variety of metal-salts towards the telechelics was studied and different supramolecular architectures were investigated, such as symmetric polymeric complexes and linear coordination polymers. Furthermore, attempts have been undertaken to prepare metallo-supramolecular cross-linked systems.
Original languageEnglish
Title of host publicationPolycondensation 2002 : Progress in step-growth polymerization and structure-property relationships of polycondensates ; 4th International Symposium on Polycondensates
Place of PublicationHamburg, Germany
PublisherWiley-VCH Verlag
Pages483-498
ISBN (Print)3-527-30703-6
DOIs
Publication statusPublished - 2003
Eventconference; International Symposium on Polycondensates ; 4 (Hamburg) : 2002.09.15-18; 2002-09-15; 2002-09-18 -
Duration: 15 Sep 200218 Sep 2002

Publication series

NameMacromolecular Symposia
Volume199
ISSN (Print)1022-1360

Conference

Conferenceconference; International Symposium on Polycondensates ; 4 (Hamburg) : 2002.09.15-18; 2002-09-15; 2002-09-18
Period15/09/0218/09/02
OtherInternational Symposium on Polycondensates ; 4 (Hamburg) : 2002.09.15-18

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