TY - GEN
T1 - Engineering with metallo-supramolecular polymers : linear coordination polymers and networks
AU - Schmatloch, S.
AU - Schubert, U.S.
PY - 2003
Y1 - 2003
N2 - Here we demonstrate the synthesis of telechelics with different spacer units and different numbers of metal-complexing units, like -methoxy--(2,2:6,2-terpyrid-4-yl)-poly(ethylenoxide)78 (1), bis(2,2:6,2-terpyrid-4-yl) di(ethylene glycol) (2), bis(2,2:6,2-terpyrid-4-yl)-poly(ethylene oxide)180 (3) and tris[(2,2:6,2-terpyrid-4-yl)-oligo (ethylenoxy-)3.33]glycerin (4) utilizing 4-chloro-2,2:6,2-terpyridine. The complexation behaviour of a variety of metal-salts towards the telechelics was studied and different supramolecular architectures were investigated, such as symmetric polymeric complexes and linear coordination polymers. Furthermore, attempts have been undertaken to prepare metallo-supramolecular cross-linked systems.
AB - Here we demonstrate the synthesis of telechelics with different spacer units and different numbers of metal-complexing units, like -methoxy--(2,2:6,2-terpyrid-4-yl)-poly(ethylenoxide)78 (1), bis(2,2:6,2-terpyrid-4-yl) di(ethylene glycol) (2), bis(2,2:6,2-terpyrid-4-yl)-poly(ethylene oxide)180 (3) and tris[(2,2:6,2-terpyrid-4-yl)-oligo (ethylenoxy-)3.33]glycerin (4) utilizing 4-chloro-2,2:6,2-terpyridine. The complexation behaviour of a variety of metal-salts towards the telechelics was studied and different supramolecular architectures were investigated, such as symmetric polymeric complexes and linear coordination polymers. Furthermore, attempts have been undertaken to prepare metallo-supramolecular cross-linked systems.
U2 - 10.1002/masy.200350940
DO - 10.1002/masy.200350940
M3 - Conference contribution
SN - 3-527-30703-6
T3 - Macromolecular Symposia
SP - 483
EP - 498
BT - Polycondensation 2002 : Progress in step-growth polymerization and structure-property relationships of polycondensates ; 4th International Symposium on Polycondensates
PB - Wiley-VCH Verlag
CY - Hamburg, Germany
T2 - conference; International Symposium on Polycondensates ; 4 (Hamburg) : 2002.09.15-18; 2002-09-15; 2002-09-18
Y2 - 15 September 2002 through 18 September 2002
ER -