Electrophilic methylthiolation and arylthiolation of aromatic compounds with thiosulfonates

J.K. Bosscher, E.W.A. Kraak, H. Kloosterziel

Research output: Contribution to journalArticleAcademicpeer-review

7 Citations (Scopus)

Abstract

Six arenes were thiolated by treatment with RSSO2R (R=Me or p-MeC6H4) and AlCl3. Thus, p-xylene gave 51% 2,5-bis(methylthio)-p-xylene and 59% 2,5-bis(p-tolylthio)-p-xylene, resp.
Original languageEnglish
Pages (from-to)1365-1365
JournalJournal of the Chemical Society [Section] D: Chemical Communications
Issue number21
DOIs
Publication statusPublished - 1971

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Aromatic compounds
4-xylene

Cite this

@article{849d4bedfea54d75910ab7ac4d40a204,
title = "Electrophilic methylthiolation and arylthiolation of aromatic compounds with thiosulfonates",
abstract = "Six arenes were thiolated by treatment with RSSO2R (R=Me or p-MeC6H4) and AlCl3. Thus, p-xylene gave 51{\%} 2,5-bis(methylthio)-p-xylene and 59{\%} 2,5-bis(p-tolylthio)-p-xylene, resp.",
author = "J.K. Bosscher and E.W.A. Kraak and H. Kloosterziel",
year = "1971",
doi = "10.1039/C2971001365a",
language = "English",
pages = "1365--1365",
journal = "Journal of the Chemical Society [Section] D: Chemical Communications",
issn = "0577-6171",
number = "21",

}

Electrophilic methylthiolation and arylthiolation of aromatic compounds with thiosulfonates. / Bosscher, J.K.; Kraak, E.W.A.; Kloosterziel, H.

In: Journal of the Chemical Society [Section] D: Chemical Communications, No. 21, 1971, p. 1365-1365.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Electrophilic methylthiolation and arylthiolation of aromatic compounds with thiosulfonates

AU - Bosscher, J.K.

AU - Kraak, E.W.A.

AU - Kloosterziel, H.

PY - 1971

Y1 - 1971

N2 - Six arenes were thiolated by treatment with RSSO2R (R=Me or p-MeC6H4) and AlCl3. Thus, p-xylene gave 51% 2,5-bis(methylthio)-p-xylene and 59% 2,5-bis(p-tolylthio)-p-xylene, resp.

AB - Six arenes were thiolated by treatment with RSSO2R (R=Me or p-MeC6H4) and AlCl3. Thus, p-xylene gave 51% 2,5-bis(methylthio)-p-xylene and 59% 2,5-bis(p-tolylthio)-p-xylene, resp.

U2 - 10.1039/C2971001365a

DO - 10.1039/C2971001365a

M3 - Article

SP - 1365

EP - 1365

JO - Journal of the Chemical Society [Section] D: Chemical Communications

JF - Journal of the Chemical Society [Section] D: Chemical Communications

SN - 0577-6171

IS - 21

ER -