Electronic modifictions in supported palladium catalysts

B.L. Mojet; M.J. Kappers; J.C. Muijsers; J.W. Niemantsverdriet; J.T. Miller; F.S. Modica; D.C. Koningsberger

doi:10.1016/S0167-2991(08)63623-X

Electronic modifictions in supported palladium catalysts

B.L. Mojet, M.J. Kappers, J.C. Muijsers, J.W. Niemantsverdriet, J.T. Miller, F.S. Modica, D.C. Koningsberger

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

42 Citations (Scopus)

Abstract

XPS and IR spectroscopy indicate that the electron density of the supported metal clusters in Pd/LTL catalysts is a function of the support acidity/alkalinity. In addition, the neopentane and propane hydrogenolysis TOF's increase with increasing support acidity from alkaline to acidic. The changes in spectroscopic and catalytic properties are due to electron deficient Pd on acidic supports, as previously proposed, and electron rich Pd on alkaline supports.

Original language	English
Title of host publication	Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994
Editors	J. Weitkamp, H. Karge, H. Pfeifer, W. Hölderich
Place of Publication	Amsterdam
Publisher	Elsevier
Pages	909-
ISBN (Print)	0-444-81847-2
DOIs	https://doi.org/10.1016/S0167-2991(08)63623-X
Publication status	Published - 1994
Event	conference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22 - Duration: 17 Jul 1994 → 22 Jul 1994

Publication series

Name	Studies in Surface Science and Catalysis
Volume	84
ISSN (Print)	0167-2991

Conference

Conference	conference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22
Period	17/07/94 → 22/07/94
Other	IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22

Fingerprint

Cite this

Mojet, B. L., Kappers, M. J., Muijsers, J. C., Niemantsverdriet, J. W., Miller, J. T., Modica, F. S., & Koningsberger, D. C. (1994). Electronic modifictions in supported palladium catalysts. In J. Weitkamp, H. Karge, H. Pfeifer, & W. Hölderich (Eds.), Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994 (pp. 909-). (Studies in Surface Science and Catalysis; Vol. 84). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(08)63623-X

Mojet, B.L. ; Kappers, M.J. ; Muijsers, J.C. ; Niemantsverdriet, J.W. ; Miller, J.T. ; Modica, F.S. ; Koningsberger, D.C. / Electronic modifictions in supported palladium catalysts. Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994. editor / J. Weitkamp ; H. Karge ; H. Pfeifer ; W. Hölderich. Amsterdam : Elsevier, 1994. pp. 909- (Studies in Surface Science and Catalysis).

@inproceedings{48d71567796e4779bbf92b79d1ccc09e,

title = "Electronic modifictions in supported palladium catalysts",

abstract = "XPS and IR spectroscopy indicate that the electron density of the supported metal clusters in Pd/LTL catalysts is a function of the support acidity/alkalinity. In addition, the neopentane and propane hydrogenolysis TOF's increase with increasing support acidity from alkaline to acidic. The changes in spectroscopic and catalytic properties are due to electron deficient Pd on acidic supports, as previously proposed, and electron rich Pd on alkaline supports.",

author = "B.L. Mojet and M.J. Kappers and J.C. Muijsers and J.W. Niemantsverdriet and J.T. Miller and F.S. Modica and D.C. Koningsberger",

year = "1994",

doi = "10.1016/S0167-2991(08)63623-X",

language = "English",

isbn = "0-444-81847-2",

series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier",

pages = "909--",

editor = "J. Weitkamp and H. Karge and H. Pfeifer and W. H{\"o}lderich",

booktitle = "Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994",

address = "Netherlands",

}

Mojet, BL, Kappers, MJ, Muijsers, JC, Niemantsverdriet, JW, Miller, JT, Modica, FS & Koningsberger, DC 1994, Electronic modifictions in supported palladium catalysts. in J Weitkamp, H Karge, H Pfeifer & W Hölderich (eds), Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994. Studies in Surface Science and Catalysis, vol. 84, Elsevier, Amsterdam, pp. 909-, conference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22, 17/07/94. https://doi.org/10.1016/S0167-2991(08)63623-X

Electronic modifictions in supported palladium catalysts. / Mojet, B.L.; Kappers, M.J.; Muijsers, J.C.; Niemantsverdriet, J.W.; Miller, J.T.; Modica, F.S.; Koningsberger, D.C.

Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994. ed. / J. Weitkamp; H. Karge; H. Pfeifer; W. Hölderich. Amsterdam : Elsevier, 1994. p. 909- (Studies in Surface Science and Catalysis; Vol. 84).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - Electronic modifictions in supported palladium catalysts

AU - Mojet, B.L.

AU - Kappers, M.J.

AU - Muijsers, J.C.

AU - Niemantsverdriet, J.W.

AU - Miller, J.T.

AU - Modica, F.S.

AU - Koningsberger, D.C.

PY - 1994

Y1 - 1994

N2 - XPS and IR spectroscopy indicate that the electron density of the supported metal clusters in Pd/LTL catalysts is a function of the support acidity/alkalinity. In addition, the neopentane and propane hydrogenolysis TOF's increase with increasing support acidity from alkaline to acidic. The changes in spectroscopic and catalytic properties are due to electron deficient Pd on acidic supports, as previously proposed, and electron rich Pd on alkaline supports.

AB - XPS and IR spectroscopy indicate that the electron density of the supported metal clusters in Pd/LTL catalysts is a function of the support acidity/alkalinity. In addition, the neopentane and propane hydrogenolysis TOF's increase with increasing support acidity from alkaline to acidic. The changes in spectroscopic and catalytic properties are due to electron deficient Pd on acidic supports, as previously proposed, and electron rich Pd on alkaline supports.

U2 - 10.1016/S0167-2991(08)63623-X

DO - 10.1016/S0167-2991(08)63623-X

M3 - Conference contribution

SN - 0-444-81847-2

T3 - Studies in Surface Science and Catalysis

SP - 909-

BT - Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994

A2 - Weitkamp, J.

A2 - Karge, H.

A2 - Pfeifer, H.

A2 - Hölderich, W.

PB - Elsevier

CY - Amsterdam

ER -

Mojet BL, Kappers MJ, Muijsers JC, Niemantsverdriet JW, Miller JT, Modica FS et al. Electronic modifictions in supported palladium catalysts. In Weitkamp J, Karge H, Pfeifer H, Hölderich W, editors, Zeolites and related microporous materials: state of the art 1994 : proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, July 17 - 22, 1994. Amsterdam: Elsevier. 1994. p. 909-. (Studies in Surface Science and Catalysis). https://doi.org/10.1016/S0167-2991(08)63623-X

Access to Document

10.1016/S0167-2991(08)63623-X