Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene

E. Guiu Rozas; M. Caporali; B. Munoz; C. Müller; M. Lutz; A.L. Spek; C. Claver; P.W.N.M. Leeuwen, van

doi:10.1021/om060121t

Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene

E. Guiu Rozas
, M. Caporali
, B. Munoz
, C. Müller
, M. Lutz
, A.L. Spek
, C. Claver
, P.W.N.M. Leeuwen, van

Research output: Contribution to journal › Article › Academic › peer-review

86 Citations (Scopus)

Abstract

The electronic character of the diphosphine ligands controls the regioselectivity of the Pd-catalyzed carbonylation of styrene. In the presence of electron-poor phosphines branched esters are produced and high activities of the catalytic systems are observed.

Original language	English
Pages (from-to)	3102-3104
Journal	Organometallics
Volume	25
Issue number	13
DOIs	https://doi.org/10.1021/om060121t
Publication status	Published - 2006

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title = "Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene",

abstract = "The electronic character of the diphosphine ligands controls the regioselectivity of the Pd-catalyzed carbonylation of styrene. In the presence of electron-poor phosphines branched esters are produced and high activities of the catalytic systems are observed.",

author = "\{Guiu Rozas\}, E. and M. Caporali and B. Munoz and C. M{\"u}ller and M. Lutz and A.L. Spek and C. Claver and \{Leeuwen, van\}, P.W.N.M.",

year = "2006",

doi = "10.1021/om060121t",

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volume = "25",

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publisher = "American Chemical Society",

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T1 - Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene

AU - Guiu Rozas, E.

AU - Caporali, M.

AU - Munoz, B.

AU - Müller, C.

AU - Lutz, M.

AU - Spek, A.L.

AU - Claver, C.

AU - Leeuwen, van, P.W.N.M.

PY - 2006

Y1 - 2006

N2 - The electronic character of the diphosphine ligands controls the regioselectivity of the Pd-catalyzed carbonylation of styrene. In the presence of electron-poor phosphines branched esters are produced and high activities of the catalytic systems are observed.

AB - The electronic character of the diphosphine ligands controls the regioselectivity of the Pd-catalyzed carbonylation of styrene. In the presence of electron-poor phosphines branched esters are produced and high activities of the catalytic systems are observed.

U2 - 10.1021/om060121t

DO - 10.1021/om060121t

M3 - Article

SN - 0276-7333

VL - 25

SP - 3102

EP - 3104

JO - Organometallics

JF - Organometallics

IS - 13

ER -

Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene

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