Electronic effect of diphosphines on the regioselectivity of the palladium-catalyzed hydroesterification of styrene

E. Guiu Rozas, M. Caporali, B. Munoz, C. Müller, M. Lutz, A.L. Spek, C. Claver, P.W.N.M. Leeuwen, van

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    70 Citations (Scopus)

    Abstract

    The electronic character of the diphosphine ligands controls the regioselectivity of the Pd-catalyzed carbonylation of styrene. In the presence of electron-poor phosphines branched esters are produced and high activities of the catalytic systems are observed.
    Original languageEnglish
    Pages (from-to)3102-3104
    JournalOrganometallics
    Volume25
    Issue number13
    DOIs
    Publication statusPublished - 2006

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