Electrochemical synthesis of Mo2C catalytical coatings for the water gas shift reaction

S.A. Kuznetsov; A. Dubrovskiy; E.V. Rebrov; J.C. Schouten

Electrochemical synthesis of Mo2C catalytical coatings for the water gas shift reaction

S.A. Kuznetsov, A. Dubrovskiy, E.V. Rebrov, J.C. Schouten

Chemical Reactor Engineering

Research output: Contribution to journal › Article › Academic › peer-review

18 Citations (Scopus)

Abstract

The electroreduction of CO3 2- ions on a molybdenum cathode in a NaCl-KCl-Li2CO3 melt was studied by cyclic voltammetry. The electrochemical synthesis of Mo2C on Molybdenum substrates has been performed at 1123 K for 7 h with a cathodic current density of 5 mA cm-2. If molybdenum carbide is present as a thin (ca. 500 nm) film on a molybdenum substrate (Mo2C/Mo), its catalytic activity in the water gas-shift reaction is enhanced by at least an order of magnitude compared to that of the bulk Mo2C phase.

Original language	English
Pages (from-to)	647-654
Journal	Zeitschrift für Naturforschung A
Volume	62a
Issue number	10/11
Publication status	Published - 2007

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title = "Electrochemical synthesis of Mo2C catalytical coatings for the water gas shift reaction",

abstract = "The electroreduction of CO3 2- ions on a molybdenum cathode in a NaCl-KCl-Li2CO3 melt was studied by cyclic voltammetry. The electrochemical synthesis of Mo2C on Molybdenum substrates has been performed at 1123 K for 7 h with a cathodic current density of 5 mA cm-2. If molybdenum carbide is present as a thin (ca. 500 nm) film on a molybdenum substrate (Mo2C/Mo), its catalytic activity in the water gas-shift reaction is enhanced by at least an order of magnitude compared to that of the bulk Mo2C phase.",

author = "S.A. Kuznetsov and A. Dubrovskiy and E.V. Rebrov and J.C. Schouten",

year = "2007",

language = "English",

volume = "62a",

pages = "647--654",

journal = "Zeitschrift f{\"u}r Naturforschung A",

issn = "0932-0784",

publisher = "Verlag der Zeitschrift fur Naturforschung",

number = "10/11",

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TY - JOUR

T1 - Electrochemical synthesis of Mo2C catalytical coatings for the water gas shift reaction

AU - Kuznetsov, S.A.

AU - Dubrovskiy, A.

AU - Rebrov, E.V.

AU - Schouten, J.C.

PY - 2007

Y1 - 2007

N2 - The electroreduction of CO3 2- ions on a molybdenum cathode in a NaCl-KCl-Li2CO3 melt was studied by cyclic voltammetry. The electrochemical synthesis of Mo2C on Molybdenum substrates has been performed at 1123 K for 7 h with a cathodic current density of 5 mA cm-2. If molybdenum carbide is present as a thin (ca. 500 nm) film on a molybdenum substrate (Mo2C/Mo), its catalytic activity in the water gas-shift reaction is enhanced by at least an order of magnitude compared to that of the bulk Mo2C phase.

AB - The electroreduction of CO3 2- ions on a molybdenum cathode in a NaCl-KCl-Li2CO3 melt was studied by cyclic voltammetry. The electrochemical synthesis of Mo2C on Molybdenum substrates has been performed at 1123 K for 7 h with a cathodic current density of 5 mA cm-2. If molybdenum carbide is present as a thin (ca. 500 nm) film on a molybdenum substrate (Mo2C/Mo), its catalytic activity in the water gas-shift reaction is enhanced by at least an order of magnitude compared to that of the bulk Mo2C phase.

M3 - Article

SN - 0932-0784

VL - 62a

SP - 647

EP - 654

JO - Zeitschrift für Naturforschung A

JF - Zeitschrift für Naturforschung A

IS - 10/11

ER -

Electrochemical synthesis of Mo2C catalytical coatings for the water gas shift reaction

Abstract

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