Electrocatalytic Pathways to the Formation of C-N Bonds

Dimitra Anastasiadou, Marta Costa Figueiredo (Corresponding author)

Research output: Contribution to journalReview articlepeer-review

11 Citations (Scopus)
41 Downloads (Pure)

Abstract

The electrochemical synthesis of organonitrogen compounds characterized by the presence of C-N bonds has emerged in the past few years as an appealing alternative for the industrial-scale production of these compounds. Given their high industrial and societal importance, finding sustainable production methods is crucial. However, their production depends on the Haber Bosch process, which has a substantial environmental impact. In response to these challenges and recognizing the scientific challenge of making C-N bonds on an electrochemical interface, there is a notable surge in interest from the scientific community. This review summarizes some of the latest contributions to electrochemical C-N bond formation (urea, amides, and amines) concerning catalyst development and reaction mechanism elucidation.

Original languageEnglish
Pages (from-to)5088-5097
Number of pages10
JournalACS Catalysis
Volume14
Issue number7
Early online date20 Mar 2024
DOIs
Publication statusPublished - 5 Apr 2024

Keywords

  • carbon dioxide electroreduction
  • C−N coupling
  • electrocatalysis
  • electrosynthesis
  • nitrogen chemistry
  • organonitrogen compounds

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