Efficient synthesis of high-spin meta-para-oligoanilines

M.P. Struijk, R.A.J. Janssen

Research output: Contribution to journalArticleAcademicpeer-review

18 Citations (Scopus)

Abstract

A series of oligo(N-methylaniline)s consisting of alternating meta and para substituted benzene rings up to 8 units has been synthesized via palladium-catalyzed coupling reactions. These oligo(N-methylaniline)s can be oxidized reversibly to the corresponding oligo(cation radical)s, which are stable at ambient temperature and possess a high-spin ground state as evidenced by ESR spectroscopy.
Original languageEnglish
Pages (from-to)2287-2290
JournalSynthetic Metals
Volume103
Issue number1-3
DOIs
Publication statusPublished - 1999

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