Efficient synthesis of high-spin meta-para-oligoanilines

M.P. Struijk; R.A.J. Janssen

doi:10.1016/S0379-6779(98)00254-9

Efficient synthesis of high-spin meta-para-oligoanilines

M.P. Struijk, R.A.J. Janssen

Research output: Contribution to journal › Article › Academic › peer-review

19 Citations (Scopus)

Abstract

A series of oligo(N-methylaniline)s consisting of alternating meta and para substituted benzene rings up to 8 units has been synthesized via palladium-catalyzed coupling reactions. These oligo(N-methylaniline)s can be oxidized reversibly to the corresponding oligo(cation radical)s, which are stable at ambient temperature and possess a high-spin ground state as evidenced by ESR spectroscopy.

Original language	English
Pages (from-to)	2287-2290
Journal	Synthetic Metals
Volume	103
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00254-9
Publication status	Published - 1999

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title = "Efficient synthesis of high-spin meta-para-oligoanilines",

abstract = "A series of oligo(N-methylaniline)s consisting of alternating meta and para substituted benzene rings up to 8 units has been synthesized via palladium-catalyzed coupling reactions. These oligo(N-methylaniline)s can be oxidized reversibly to the corresponding oligo(cation radical)s, which are stable at ambient temperature and possess a high-spin ground state as evidenced by ESR spectroscopy.",

author = "M.P. Struijk and R.A.J. Janssen",

year = "1999",

doi = "10.1016/S0379-6779(98)00254-9",

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AU - Struijk, M.P.

AU - Janssen, R.A.J.

PY - 1999

Y1 - 1999

N2 - A series of oligo(N-methylaniline)s consisting of alternating meta and para substituted benzene rings up to 8 units has been synthesized via palladium-catalyzed coupling reactions. These oligo(N-methylaniline)s can be oxidized reversibly to the corresponding oligo(cation radical)s, which are stable at ambient temperature and possess a high-spin ground state as evidenced by ESR spectroscopy.

AB - A series of oligo(N-methylaniline)s consisting of alternating meta and para substituted benzene rings up to 8 units has been synthesized via palladium-catalyzed coupling reactions. These oligo(N-methylaniline)s can be oxidized reversibly to the corresponding oligo(cation radical)s, which are stable at ambient temperature and possess a high-spin ground state as evidenced by ESR spectroscopy.

U2 - 10.1016/S0379-6779(98)00254-9

DO - 10.1016/S0379-6779(98)00254-9

M3 - Article

SN - 0379-6779

VL - 103

SP - 2287

EP - 2290

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Efficient synthesis of high-spin meta-para-oligoanilines

Abstract

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