Abstract
The catalytic performance of RePt/CeO2-TiO2 catalysts for the WGS reaction under conditions compatible with membrane reactor was investigated. The WGS activity and stability of the Pt/CeO2-TiO2 catalyst was significantly influenced by the addition of rhenium. The intrinsic WGS activity per atom of platinum improves with the addition of Re to Pt/CeO2-TiO2 catalyst. The addition of rhenium also has a beneficial effect on its stability under WGS conditions compatible with membrane reactor use. The improvement in WGS activity and stability is proposed to be associated with the improvement in the reduction behavior of the highly dispersed CeO2 and ReO x species present in the bimetallic RePt catalyst respect to the monometallic Pt/CeTi counterpart and to the presence of rhenium species in close contact with Pt that could introduce an additional redox activity sites stable under WGS conditions and/or prevent the sintering of Pt crystallites under WGS conditions.
| Original language | English |
|---|---|
| Pages (from-to) | 95-102 |
| Journal | Catalysis Today |
| Volume | 268 |
| DOIs | |
| Publication status | Published - 15 Jun 2016 |
| Event | 12th International Conference on Catalysis in Membrane Reactors (ICCMR12) - Szczecin, Poland Duration: 22 Jun 2015 → 25 Jun 2015 Conference number: 12 http://www.iccmr12.zut.edu.pl/ |
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Keywords
- Ceria
- Fluidization
- Membrane reactor
- Platinum
- Rhenium
- Titania
- WGS
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Effect of Re addition on the WGS activity and stability of Pt/CeO2-TiO2 catalyst for membrane reactor applications. / del Villar, V.; Barrio, L.; Helmi Siasi Farimani, Arash; Annaland, M. Van Sint; Gallucci, F.; Fierro, J.L.G.; Navarro, R.M.
In: Catalysis Today, Vol. 268, 15.06.2016, p. 95-102.Research output: Contribution to journal › Article › Academic › peer-review
TY - JOUR
T1 - Effect of Re addition on the WGS activity and stability of Pt/CeO2-TiO2 catalyst for membrane reactor applications
AU - del Villar, V.
AU - Barrio, L.
AU - Helmi Siasi Farimani, Arash
AU - Annaland, M. Van Sint
AU - Gallucci, F.
AU - Fierro, J.L.G.
AU - Navarro, R.M.
PY - 2016/6/15
Y1 - 2016/6/15
N2 - The catalytic performance of RePt/CeO2-TiO2 catalysts for the WGS reaction under conditions compatible with membrane reactor was investigated. The WGS activity and stability of the Pt/CeO2-TiO2 catalyst was significantly influenced by the addition of rhenium. The intrinsic WGS activity per atom of platinum improves with the addition of Re to Pt/CeO2-TiO2 catalyst. The addition of rhenium also has a beneficial effect on its stability under WGS conditions compatible with membrane reactor use. The improvement in WGS activity and stability is proposed to be associated with the improvement in the reduction behavior of the highly dispersed CeO2 and ReO x species present in the bimetallic RePt catalyst respect to the monometallic Pt/CeTi counterpart and to the presence of rhenium species in close contact with Pt that could introduce an additional redox activity sites stable under WGS conditions and/or prevent the sintering of Pt crystallites under WGS conditions.
AB - The catalytic performance of RePt/CeO2-TiO2 catalysts for the WGS reaction under conditions compatible with membrane reactor was investigated. The WGS activity and stability of the Pt/CeO2-TiO2 catalyst was significantly influenced by the addition of rhenium. The intrinsic WGS activity per atom of platinum improves with the addition of Re to Pt/CeO2-TiO2 catalyst. The addition of rhenium also has a beneficial effect on its stability under WGS conditions compatible with membrane reactor use. The improvement in WGS activity and stability is proposed to be associated with the improvement in the reduction behavior of the highly dispersed CeO2 and ReO x species present in the bimetallic RePt catalyst respect to the monometallic Pt/CeTi counterpart and to the presence of rhenium species in close contact with Pt that could introduce an additional redox activity sites stable under WGS conditions and/or prevent the sintering of Pt crystallites under WGS conditions.
KW - Ceria
KW - Fluidization
KW - Membrane reactor
KW - Platinum
KW - Rhenium
KW - Titania
KW - WGS
UR - http://www.scopus.com/inward/record.url?scp=84949894804&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2015.11.013
DO - 10.1016/j.cattod.2015.11.013
M3 - Article
AN - SCOPUS:84949894804
VL - 268
SP - 95
EP - 102
JO - Catalysis Today
JF - Catalysis Today
SN - 0920-5861
ER -