Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)

E. Peeters; R.A.J. Janssen; E.W. Meijer

doi:10.1016/S0379-6779(98)01388-5

Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)

E. Peeters, R.A.J. Janssen, E.W. Meijer

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A series of 11 chiral dialkoxy substituted poly(p-phenylene vinylene)s has been synthesized to investigate the effect of the regioregularity of the substitution pattern on the chiroptical properties of these materials in thin films. Regioregularly substituted chiral PPV derivs. exhibit a strong optical activity in the p-p* transition of the polymer backbone. A marked decrease in optical activity is obsd. for regioirregularly substituted polymers as a result of a decreased degree of interchain order in the morphol. of thin films

Original language	English
Pages (from-to)	1105-1106
Number of pages	2
Journal	Synthetic Metals
Volume	102
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)01388-5
Publication status	Published - 1999

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title = "Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)",

abstract = "A series of 11 chiral dialkoxy substituted poly(p-phenylene vinylene)s has been synthesized to investigate the effect of the regioregularity of the substitution pattern on the chiroptical properties of these materials in thin films. Regioregularly substituted chiral PPV derivs. exhibit a strong optical activity in the p-p* transition of the polymer backbone. A marked decrease in optical activity is obsd. for regioirregularly substituted polymers as a result of a decreased degree of interchain order in the morphol. of thin films",

author = "E. Peeters and R.A.J. Janssen and E.W. Meijer",

year = "1999",

doi = "10.1016/S0379-6779(98)01388-5",

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T1 - Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)

AU - Peeters, E.

AU - Janssen, R.A.J.

AU - Meijer, E.W.

PY - 1999

Y1 - 1999

N2 - A series of 11 chiral dialkoxy substituted poly(p-phenylene vinylene)s has been synthesized to investigate the effect of the regioregularity of the substitution pattern on the chiroptical properties of these materials in thin films. Regioregularly substituted chiral PPV derivs. exhibit a strong optical activity in the p-p* transition of the polymer backbone. A marked decrease in optical activity is obsd. for regioirregularly substituted polymers as a result of a decreased degree of interchain order in the morphol. of thin films

AB - A series of 11 chiral dialkoxy substituted poly(p-phenylene vinylene)s has been synthesized to investigate the effect of the regioregularity of the substitution pattern on the chiroptical properties of these materials in thin films. Regioregularly substituted chiral PPV derivs. exhibit a strong optical activity in the p-p* transition of the polymer backbone. A marked decrease in optical activity is obsd. for regioirregularly substituted polymers as a result of a decreased degree of interchain order in the morphol. of thin films

U2 - 10.1016/S0379-6779(98)01388-5

DO - 10.1016/S0379-6779(98)01388-5

M3 - Article

SN - 0379-6779

VL - 102

SP - 1105

EP - 1106

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Effect of intrachain order on the chiroptical properties of chiral poly(P-phenylene vinylenes)

Abstract

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