Editors' Choice—Flooded by Success: On the Role of Electrode Wettability in CO2 Electrolyzers that Generate Liquid Products

McLain E. Leonard, Michael J. Orella, Nicholas Aiello, Yuriy Román-Leshkov, Antoni Forner Cuenca, Fikile R. Brushett (Corresponding author)

Research output: Contribution to journalArticleAcademicpeer-review

1 Citation (Scopus)

Abstract

Economic operation of carbon dioxide (CO2) electrolyzers generating liquid products will likely require high reactant conversions and product concentrations, conditions anticipated to challenge existing gas diffusion electrodes (GDEs). Notably, electrode wettability will increase as lower surface tension products (e.g., formic acid, alcohols) are introduced into electrolyte streams, potentially leading to flooding. To understand the hydraulically stable operating envelopes in mixed aqueous-organic liquid domains, we connect intrinsic electrode wettability descriptors to operating parameters such as electrolyte flow rate and current. We first measure contact angles of water-organic product dilutions on polytetrafluoroethylene (PTFE) and graphite surfaces as planar analogues for GDE components. We then use material balances around the reactive gas-liquid-solid interface to calculate product mass fractions as functions of water sweep rate and current. Product composition maps visualize the extent to which changes in cell performance influence capillary pressure, a determinant of GDE saturation. Analyses suggest that formic acid mixtures pose little risk for GDE flooding across a wide range of conditions, but effluents containing <30% alcohol by mass may cause flooding. This study reveals opportunities to integrate microstructural features and oleophobic surface treatments into GDEs to repel aqueous-organic mixtures and expand the window of stable operating conditions.
Original languageEnglish
Article number124521
Number of pages11
JournalJournal of the Electrochemical Society
Volume167
Issue number12
DOIs
Publication statusPublished - 9 Jan 2020

Keywords

  • carbon dioxide
  • electrochemical reduction
  • flooding
  • gas diffusion electrode
  • organic products
  • wettability

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