TY - JOUR
T1 - Disperse amphiphilic submicron particles as non-covalent supports for cationic homogeneous catalysts
AU - Sablong, R.J.
AU - Vlugt, van der, J.I.
AU - Thomann, R.
AU - Mecking, S.
AU - Vogt, D.
PY - 2005
Y1 - 2005
N2 - A simple method for the effective immobilization of homogeneous catalysts on polystyrene colloids via non-covalent binding is demonstrated. Stable latices with sufficiently high loading of accessible borate anions are prepared via emulsion polymerization. Incorporation of cationic rhodium complexes, supported via their borate counter-anion is efficient, and these supported homogeneous catalysts maintain constant catalytic activity for CC hydrogenation during several recycles, with very low metal leaching.
AB - A simple method for the effective immobilization of homogeneous catalysts on polystyrene colloids via non-covalent binding is demonstrated. Stable latices with sufficiently high loading of accessible borate anions are prepared via emulsion polymerization. Incorporation of cationic rhodium complexes, supported via their borate counter-anion is efficient, and these supported homogeneous catalysts maintain constant catalytic activity for CC hydrogenation during several recycles, with very low metal leaching.
U2 - 10.1002/adsc.200404284
DO - 10.1002/adsc.200404284
M3 - Article
SN - 1615-4150
VL - 347
SP - 633
EP - 636
JO - Advanced Synthesis & Catalysis
JF - Advanced Synthesis & Catalysis
IS - 5
ER -