Disperse amphiphilic submicron particles as non-covalent supports for cationic homogeneous catalysts

R.J. Sablong, J.I. Vlugt, van der, R. Thomann, S. Mecking, D. Vogt

    Research output: Contribution to journalArticleAcademicpeer-review

    18 Citations (Scopus)

    Abstract

    A simple method for the effective immobilization of homogeneous catalysts on polystyrene colloids via non-covalent binding is demonstrated. Stable latices with sufficiently high loading of accessible borate anions are prepared via emulsion polymerization. Incorporation of cationic rhodium complexes, supported via their borate counter-anion is efficient, and these supported homogeneous catalysts maintain constant catalytic activity for CC hydrogenation during several recycles, with very low metal leaching.
    Original languageEnglish
    Pages (from-to)633-636
    JournalAdvanced Synthesis & Catalysis
    Volume347
    Issue number5
    DOIs
    Publication statusPublished - 2005

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