Dinuclair copper(I)thiolate complexes with a bridging noninnocent PNP ligand

J.I. Vlugt, van der, R. C. Bauer, Y. Gloaguen, M.K. Rong, M. Lutz

Research output: Contribution to journalArticleAcademicpeer-review

53 Citations (Scopus)
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Abstract

Noninnocent, but not guilty: The versatile PNPtBu scaffold acts as a noninnocent, pseudobridging ligand toward CuX (ratio 1:2), resulting in a 1D-coordination chain. Ligand dearomatization by using base and subsequent addition of thiols leads to the unique, asymmetrically substituted, dinuclear Cu species with reactive Br coligands and the versatile PNPtBu ligand that bridges the two Cu centers (see scheme).
Original languageEnglish
Pages (from-to)3850-3854
Number of pages5
JournalChemistry : A European Journal
Volume17
Issue number14
DOIs
Publication statusPublished - 2011

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