Determination of valence and coordination of iron in oxidic compounds by means of the iron X-ray fluorescence emission spectrum

A.S. Koster, G.D. Rieck

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Abstract

The dependence of the X-ray fluorescence iron Kß spectrum of oxidic iron compounds on chemical and crystallographic structure was studied. The position of the line Kß5 is mainly determined by the valence of the iron, the position of Kß1,3 is also influenced by the coordination of the iron ions. The satellites occuring in the Kß spectrum give, in a qualitative way, additional information about structure.
Original languageEnglish
Pages (from-to)2505-2510
Number of pages6
JournalJournal of Physics and Chemistry of Solids
Volume31
Issue number11
DOIs
Publication statusPublished - 1970

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