@inproceedings{825c6ea1b76c458c9c62fc9eb16efc0f,
title = "CrAPO-catalyzed oxidations of alkylaromatics and alcohols with TBHP in the liquid phase (redox molecular sieves, part 8)",
abstract = "Chromium-substituted aluminophosphates were synthesized and characterized. Chromium-aluminophosphoates (CrAPO-5 and CrAPO-11) catalyze the oxidn. of ethylbenzene, p-ethyltoluene, n-propylbenzene, n-butylbenzene, diphenylmethane, p-ethylanisole, and primary, secondary benzylic alcs. to the corresponding ketones or acids with TBHP at 80-100 DegC. The main parameters affecting reaction rates are competitive adsorption and diffusion. The activity of used CrAPO-5 is completely recovered by recalcination at 500 DegC. Oxidn. of 4-methoxybenzyl alc. gave 4-methoxybenzoic acid (100% conversion of reactant; 87% selectivity toward product).",
author = "J.D. Chen and M.J. Haanepen and {Hooff, van}, J.H.C. and R.A. Sheldon",
year = "1994",
doi = "10.1016/S0167-2991(08)63631-9",
language = "English",
isbn = "0-444-81847-2",
series = "Studies in Surface Science and Catalysis",
publisher = "Elsevier",
pages = "973--980",
editor = "J. Weitkamp and H.G. Karge and H. Pfeifer and W. Holderich",
booktitle = "Proceedings of the 10th International Zeolite Conference: Zeolites and Related Microporous Materials: State of the Art 1994; 17-22 July 1994, Garmisch-Partenkirchen, Germany",
address = "Netherlands",
note = "conference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22 ; Conference date: 17-07-1994 Through 22-07-1994",
}