Coplanarity by hydrogen bonding in well-defined oligoheterocycles

J.A.J.M. Vekemans, L. Groenendaal, A.R.A. Palmans, D.A.P. Delnoye, H.A.M. Mullekom, van, E.W. Meijer

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Abstract

(Hetero)aryl-aryl coupling for covalent bonding and intramol. hydrogen bond formation for establishing the secondary structure have been united to design and construct well-defined, functionalized macromols. The suitability of azaheterocyclic units to realize this concept is exemplified by star shaped discotic liq. cryst. compds. and ladder-type conjugated copolymers. A review with >40 refs
Original languageEnglish
Pages (from-to)659-674
JournalBulletin des Societes Chimiques Belges
Volume105
Publication statusPublished - 1996

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