Controlling the 3D nanoscale organization of bulk heterojunction polymer solar cells

S.S. Bavel, van; E. Sourty; G. With, de; J. Loos

doi:10.1142/S0256767909003686

Controlling the 3D nanoscale organization of bulk heterojunction polymer solar cells

S.S. Bavel, van, E. Sourty, G. With, de, J. Loos

Materials and Interface Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

In this study, the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography. After annealing treatment, either at elevated temperature or during slow solvent evaporation, nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer. Such a tailored morphology accounts for the considerable increase of the power conversion efficiency in corresponding solar cell devices.

Original language	English
Pages (from-to)	85-92
Journal	Chinese Journal of Polymer Science
Volume	27
Issue number	1
DOIs	https://doi.org/10.1142/S0256767909003686
Publication status	Published - 2009

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abstract = "In this study, the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography. After annealing treatment, either at elevated temperature or during slow solvent evaporation, nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer. Such a tailored morphology accounts for the considerable increase of the power conversion efficiency in corresponding solar cell devices.",

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AU - Bavel, van, S.S.

AU - Sourty, E.

AU - With, de, G.

AU - Loos, J.

PY - 2009

Y1 - 2009

N2 - In this study, the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography. After annealing treatment, either at elevated temperature or during slow solvent evaporation, nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer. Such a tailored morphology accounts for the considerable increase of the power conversion efficiency in corresponding solar cell devices.

AB - In this study, the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography. After annealing treatment, either at elevated temperature or during slow solvent evaporation, nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer. Such a tailored morphology accounts for the considerable increase of the power conversion efficiency in corresponding solar cell devices.

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DO - 10.1142/S0256767909003686

M3 - Article

VL - 27

SP - 85

EP - 92

JO - Chinese Journal of Polymer Science

JF - Chinese Journal of Polymer Science

SN - 0256-7679

IS - 1

ER -

Controlling the 3D nanoscale organization of bulk heterojunction polymer solar cells

Abstract

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