Controlled synthesis and morphological characterization of nanometer-sized ionic crosslinking domains in PMMA

S. Karanam; J.G.P. Goossens; P.J. Lemstra

Controlled synthesis and morphological characterization of nanometer-sized ionic crosslinking domains in PMMA

S. Karanam, J.G.P. Goossens, P.J. Lemstra

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

Abstract

The controlled synthesis of methacrylate di- and triblock ionomers was achieved by copper mediated atom transfer radical pPOLYmn. (ATRP). The synthetic strategy involves the use of tert-Bu methacrylate (tBMA) as the precursor for the methacrylic acid (MAA) block to obtain di- and triblock copPOLYmers with PMMA as the center block at various ratios of tBMA to MMA.PMMA macroinitiators with defined mol. wt. and high chain end functionality successfully initiate the copPOLYmn. of tBMA resulting in block copPOLYmers with excellent control of mol. wt. and low PDI.Normal Phase Gradient PPOLYmer Elution Chromatog. (NP-GPEC) was used to prove the existence of block copPOLYmer structure. Trifluoroacetic acid was used in the selective hydrPOLYsis of the Pt-BMA block resulting in methacrylic acid based blocks, which were soln. neutralized by ethanolic potassium hydroxide resulting in PMMA ionomers. The microphase sepn. and the formation of nanometer sized ionic domains varying from 12- 40 nm were confirmed by SAXS measurements. Salient features of the synthesis and morphol. of precursors/ionomers will be presented

Original language	English
Title of host publication	Abstracts of Papers, 225th ACS National Meeting, New Orleans, LA, United States, March 23-27, 2003 (2003)
Place of Publication	Washington, D. C
Publisher	American Chemical Society
Pages	POLY-044
ISBN (Print)	0-8412-3872-3
Publication status	Published - 2003
Event	225th ACS National Meeting - New Orleans, United States Duration: 23 Mar 2003 → 27 Mar 2003

Conference

Conference	225th ACS National Meeting
Country/Territory	United States
City	New Orleans
Period	23/03/03 → 27/03/03

Cite this

@inproceedings{64389ce0ed1849a58a51ca499d8c0a96,

title = "Controlled synthesis and morphological characterization of nanometer-sized ionic crosslinking domains in PMMA",

abstract = "The controlled synthesis of methacrylate di- and triblock ionomers was achieved by copper mediated atom transfer radical pPOLYmn. (ATRP). The synthetic strategy involves the use of tert-Bu methacrylate (tBMA) as the precursor for the methacrylic acid (MAA) block to obtain di- and triblock copPOLYmers with PMMA as the center block at various ratios of tBMA to MMA.PMMA macroinitiators with defined mol. wt. and high chain end functionality successfully initiate the copPOLYmn. of tBMA resulting in block copPOLYmers with excellent control of mol. wt. and low PDI.Normal Phase Gradient PPOLYmer Elution Chromatog. (NP-GPEC) was used to prove the existence of block copPOLYmer structure. Trifluoroacetic acid was used in the selective hydrPOLYsis of the Pt-BMA block resulting in methacrylic acid based blocks, which were soln. neutralized by ethanolic potassium hydroxide resulting in PMMA ionomers. The microphase sepn. and the formation of nanometer sized ionic domains varying from 12- 40 nm were confirmed by SAXS measurements. Salient features of the synthesis and morphol. of precursors/ionomers will be presented",

author = "S. Karanam and J.G.P. Goossens and P.J. Lemstra",

year = "2003",

language = "English",

isbn = "0-8412-3872-3",

pages = "POLY--044",

booktitle = "Abstracts of Papers, 225th ACS National Meeting, New Orleans, LA, United States, March 23-27, 2003 (2003)",

publisher = "American Chemical Society",

address = "United States",

note = "225th ACS National Meeting ; Conference date: 23-03-2003 Through 27-03-2003",

}

Karanam, S, Goossens, JGP & Lemstra, PJ 2003, Controlled synthesis and morphological characterization of nanometer-sized ionic crosslinking domains in PMMA. in Abstracts of Papers, 225th ACS National Meeting, New Orleans, LA, United States, March 23-27, 2003 (2003). American Chemical Society, Washington, D. C, pp. POLY-044, 225th ACS National Meeting, New Orleans, Louisiana, United States, 23/03/03.

Controlled synthesis and morphological characterization of nanometer-sized ionic crosslinking domains in PMMA. / Karanam, S.; Goossens, J.G.P.; Lemstra, P.J.
Abstracts of Papers, 225th ACS National Meeting, New Orleans, LA, United States, March 23-27, 2003 (2003). Washington, D. C: American Chemical Society, 2003. p. POLY-044.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - Controlled synthesis and morphological characterization of nanometer-sized ionic crosslinking domains in PMMA

AU - Karanam, S.

AU - Goossens, J.G.P.

AU - Lemstra, P.J.

PY - 2003

Y1 - 2003

N2 - The controlled synthesis of methacrylate di- and triblock ionomers was achieved by copper mediated atom transfer radical pPOLYmn. (ATRP). The synthetic strategy involves the use of tert-Bu methacrylate (tBMA) as the precursor for the methacrylic acid (MAA) block to obtain di- and triblock copPOLYmers with PMMA as the center block at various ratios of tBMA to MMA.PMMA macroinitiators with defined mol. wt. and high chain end functionality successfully initiate the copPOLYmn. of tBMA resulting in block copPOLYmers with excellent control of mol. wt. and low PDI.Normal Phase Gradient PPOLYmer Elution Chromatog. (NP-GPEC) was used to prove the existence of block copPOLYmer structure. Trifluoroacetic acid was used in the selective hydrPOLYsis of the Pt-BMA block resulting in methacrylic acid based blocks, which were soln. neutralized by ethanolic potassium hydroxide resulting in PMMA ionomers. The microphase sepn. and the formation of nanometer sized ionic domains varying from 12- 40 nm were confirmed by SAXS measurements. Salient features of the synthesis and morphol. of precursors/ionomers will be presented

AB - The controlled synthesis of methacrylate di- and triblock ionomers was achieved by copper mediated atom transfer radical pPOLYmn. (ATRP). The synthetic strategy involves the use of tert-Bu methacrylate (tBMA) as the precursor for the methacrylic acid (MAA) block to obtain di- and triblock copPOLYmers with PMMA as the center block at various ratios of tBMA to MMA.PMMA macroinitiators with defined mol. wt. and high chain end functionality successfully initiate the copPOLYmn. of tBMA resulting in block copPOLYmers with excellent control of mol. wt. and low PDI.Normal Phase Gradient PPOLYmer Elution Chromatog. (NP-GPEC) was used to prove the existence of block copPOLYmer structure. Trifluoroacetic acid was used in the selective hydrPOLYsis of the Pt-BMA block resulting in methacrylic acid based blocks, which were soln. neutralized by ethanolic potassium hydroxide resulting in PMMA ionomers. The microphase sepn. and the formation of nanometer sized ionic domains varying from 12- 40 nm were confirmed by SAXS measurements. Salient features of the synthesis and morphol. of precursors/ionomers will be presented

M3 - Conference contribution

SN - 0-8412-3872-3

SP - POLY-044

BT - Abstracts of Papers, 225th ACS National Meeting, New Orleans, LA, United States, March 23-27, 2003 (2003)

PB - American Chemical Society

CY - Washington, D. C

T2 - 225th ACS National Meeting

Y2 - 23 March 2003 through 27 March 2003

ER -

Controlled synthesis and morphological characterization of nanometer-sized ionic crosslinking domains in PMMA

Abstract

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