Control of the molecular weight distribution in continuous emulsion polymerization of a pulsed sieve plate column

N.M.B. Smeets; B.A.J. Dautzenberg; J.P.A. Heuts; J. Meuldijk; A.M. Herk, van

doi:10.1002/masy.200950117

Control of the molecular weight distribution in continuous emulsion polymerization of a pulsed sieve plate column

N.M.B. Smeets, B.A.J. Dautzenberg, J.P.A. Heuts, J. Meuldijk, A.M. Herk, van

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Control of the molecular weight distribution in continuous emulsion polymerization in a pulsed sieve plate column (PSPC) is experimentally studied. A global model, based on the Mayo equation, incoporating catalyst partitioning and deactivation was used to quantitatively illustrate the effect of the COBF addition on the instantaneous degree of polymerization in a batch reactor and the PSPC. Operating conditions have a strong influence on the cumulative molecular weight distribution of the latex product produced in the PSPC.

Original language	English
Pages (from-to)	149-157
Journal	Macromolecular Symposia
Volume	275-276
Issue number	Microstructural Control in Free-Radical Polymerization
DOIs	https://doi.org/10.1002/masy.200950117
Publication status	Published - 2009

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abstract = "Control of the molecular weight distribution in continuous emulsion polymerization in a pulsed sieve plate column (PSPC) is experimentally studied. A global model, based on the Mayo equation, incoporating catalyst partitioning and deactivation was used to quantitatively illustrate the effect of the COBF addition on the instantaneous degree of polymerization in a batch reactor and the PSPC. Operating conditions have a strong influence on the cumulative molecular weight distribution of the latex product produced in the PSPC.",

author = "N.M.B. Smeets and B.A.J. Dautzenberg and J.P.A. Heuts and J. Meuldijk and {Herk, van}, A.M.",

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Control of the molecular weight distribution in continuous emulsion polymerization of a pulsed sieve plate column. / Smeets, N.M.B.; Dautzenberg, B.A.J.; Heuts, J.P.A.; Meuldijk, J.; Herk, van, A.M.

In: Macromolecular Symposia, Vol. 275-276, No. Microstructural Control in Free-Radical Polymerization, 2009, p. 149-157.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Control of the molecular weight distribution in continuous emulsion polymerization of a pulsed sieve plate column

AU - Smeets, N.M.B.

AU - Dautzenberg, B.A.J.

AU - Heuts, J.P.A.

AU - Meuldijk, J.

AU - Herk, van, A.M.

PY - 2009

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N2 - Control of the molecular weight distribution in continuous emulsion polymerization in a pulsed sieve plate column (PSPC) is experimentally studied. A global model, based on the Mayo equation, incoporating catalyst partitioning and deactivation was used to quantitatively illustrate the effect of the COBF addition on the instantaneous degree of polymerization in a batch reactor and the PSPC. Operating conditions have a strong influence on the cumulative molecular weight distribution of the latex product produced in the PSPC.

AB - Control of the molecular weight distribution in continuous emulsion polymerization in a pulsed sieve plate column (PSPC) is experimentally studied. A global model, based on the Mayo equation, incoporating catalyst partitioning and deactivation was used to quantitatively illustrate the effect of the COBF addition on the instantaneous degree of polymerization in a batch reactor and the PSPC. Operating conditions have a strong influence on the cumulative molecular weight distribution of the latex product produced in the PSPC.

U2 - 10.1002/masy.200950117

DO - 10.1002/masy.200950117

M3 - Article

VL - 275-276

SP - 149

EP - 157

JO - Macromolecular Symposia

JF - Macromolecular Symposia

SN - 1022-1360

IS - Microstructural Control in Free-Radical Polymerization

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