TY - JOUR
T1 - Continuous rhodium-catalyzed hydroformylation of 1-octene with polyhedral oligomeric silsesquioxanes (POSS) enlarged triphenylphosphine
AU - Janssen, M.C.C.
AU - Wilting, J.B.M.
AU - Müller, C.
AU - Vogt, D.
PY - 2010
Y1 - 2010
N2 - Go with the flow: Homogeneous catalyst recycling can be applied to the production of aldehydes in a continuous flow nanofiltration reactor (see picture) that can operate for an unprecedented period of up to two weeks without showing typical deactivation or leaching phenomena. The catalyst is based on a bulky, rigid, and robust silsesquioxane-modified PPh3 ligand, and combines efficient recovery with high activity and selectivity.
AB - Go with the flow: Homogeneous catalyst recycling can be applied to the production of aldehydes in a continuous flow nanofiltration reactor (see picture) that can operate for an unprecedented period of up to two weeks without showing typical deactivation or leaching phenomena. The catalyst is based on a bulky, rigid, and robust silsesquioxane-modified PPh3 ligand, and combines efficient recovery with high activity and selectivity.
U2 - 10.1002/anie.201001926
DO - 10.1002/anie.201001926
M3 - Article
C2 - 20827743
VL - 49
SP - 7738
EP - 7741
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 0570-0833
IS - 42
ER -