Continuous rhodium-catalyzed hydroformylation of 1-octene with polyhedral oligomeric silsesquioxanes (POSS) enlarged triphenylphosphine

M.C.C. Janssen, J.B.M. Wilting, C. Müller, D. Vogt

Research output: Contribution to journalArticleAcademicpeer-review

65 Citations (Scopus)

Abstract

Go with the flow: Homogeneous catalyst recycling can be applied to the production of aldehydes in a continuous flow nanofiltration reactor (see picture) that can operate for an unprecedented period of up to two weeks without showing typical deactivation or leaching phenomena. The catalyst is based on a bulky, rigid, and robust silsesquioxane-modified PPh3 ligand, and combines efficient recovery with high activity and selectivity.
Original languageEnglish
Pages (from-to)7738-7741
JournalAngewandte Chemie - International Edition
Volume49
Issue number42
DOIs
Publication statusPublished - 2010

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