Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes

J.A. Berrocal; F. Di Meo; M. García-Iglesias; R.P.J. Gosens; E.W. Meijer; M. Linares; A.R.A. Palmans

doi:10.1039/c6cc05593a

Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes

J.A. Berrocal
, F. Di Meo
, M. García-Iglesias
, R.P.J. Gosens
, E.W. Meijer
, M. Linares
, A.R.A. Palmans

Institute for Complex Molecular Systems

Research output: Contribution to journal › Article › Academic › peer-review

28 Citations (Scopus)

179 Downloads (Pure)

Abstract

We report the synthesis and self-assembly of chiral, conformationally flexible C3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2 : 1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes.

Original language	English
Pages (from-to)	10870-10873
Number of pages	4
Journal	Chemical Communications, ChemComm
Volume	52
Issue number	72
DOIs	https://doi.org/10.1039/c6cc05593a
Publication status	Published - 18 Sept 2016

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10.1039/c6cc05593a

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abstract = "We report the synthesis and self-assembly of chiral, conformationally flexible C3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2 : 1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes.",

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AU - García-Iglesias, M.

AU - Gosens, R.P.J.

AU - Meijer, E.W.

AU - Linares, M.

AU - Palmans, A.R.A.

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AB - We report the synthesis and self-assembly of chiral, conformationally flexible C3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2 : 1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes.

KW - Journal Article

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Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes

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