Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide

R. Hoogenboom, R.M. Paulus, M.W.M. Fijten, U.S. Schubert

Research output: Contribution to journalArticleAcademicpeer-review

31 Citations (Scopus)

Abstract

The monomer concentration for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide was optimized utilizing high-throughput experimentation methods. Detailed 1H-NMR spectroscopic investigations were performed to understand the mechanistic aspects of the observed concentration effects. Finally, the improved polymerization concentration was applied for the synthesis of higher molecular weight (> 10,000 Da) poly(2-ethyl-2-oxazoline)s.
Original languageEnglish
Pages (from-to)1487-1497
Number of pages11
JournalJournal of Polymer Science, Part A: Polymer Chemistry
Volume43
Issue number7
DOIs
Publication statusPublished - 2005

Fingerprint

Cationic polymerization
Ring opening polymerization
Monomers
Molecular weight
Polymerization
Throughput
Nuclear magnetic resonance
dimethylacetamide
poly(2-ethyl-2-oxazoline)
2-ethyl-2-oxazoline

Cite this

Hoogenboom, R. ; Paulus, R.M. ; Fijten, M.W.M. ; Schubert, U.S. / Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide. In: Journal of Polymer Science, Part A: Polymer Chemistry. 2005 ; Vol. 43, No. 7. pp. 1487-1497.
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Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide. / Hoogenboom, R.; Paulus, R.M.; Fijten, M.W.M.; Schubert, U.S.

In: Journal of Polymer Science, Part A: Polymer Chemistry, Vol. 43, No. 7, 2005, p. 1487-1497.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide

AU - Hoogenboom, R.

AU - Paulus, R.M.

AU - Fijten, M.W.M.

AU - Schubert, U.S.

PY - 2005

Y1 - 2005

N2 - The monomer concentration for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide was optimized utilizing high-throughput experimentation methods. Detailed 1H-NMR spectroscopic investigations were performed to understand the mechanistic aspects of the observed concentration effects. Finally, the improved polymerization concentration was applied for the synthesis of higher molecular weight (> 10,000 Da) poly(2-ethyl-2-oxazoline)s.

AB - The monomer concentration for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide was optimized utilizing high-throughput experimentation methods. Detailed 1H-NMR spectroscopic investigations were performed to understand the mechanistic aspects of the observed concentration effects. Finally, the improved polymerization concentration was applied for the synthesis of higher molecular weight (> 10,000 Da) poly(2-ethyl-2-oxazoline)s.

U2 - 10.1002/pola.20603

DO - 10.1002/pola.20603

M3 - Article

VL - 43

SP - 1487

EP - 1497

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

SN - 0887-624X

IS - 7

ER -