Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide

R. Hoogenboom; R.M. Paulus; M.W.M. Fijten; U.S. Schubert

doi:10.1002/pola.20603

Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide

R. Hoogenboom, R.M. Paulus, M.W.M. Fijten, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

40 Citations (Scopus)

Abstract

The monomer concentration for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide was optimized utilizing high-throughput experimentation methods. Detailed 1H-NMR spectroscopic investigations were performed to understand the mechanistic aspects of the observed concentration effects. Finally, the improved polymerization concentration was applied for the synthesis of higher molecular weight (> 10,000 Da) poly(2-ethyl-2-oxazoline)s.

Original language	English
Pages (from-to)	1487-1497
Number of pages	11
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	43
Issue number	7
DOIs	https://doi.org/10.1002/pola.20603
Publication status	Published - 2005

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title = "Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide",

abstract = "The monomer concentration for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide was optimized utilizing high-throughput experimentation methods. Detailed 1H-NMR spectroscopic investigations were performed to understand the mechanistic aspects of the observed concentration effects. Finally, the improved polymerization concentration was applied for the synthesis of higher molecular weight (> 10,000 Da) poly(2-ethyl-2-oxazoline)s.",

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AU - Hoogenboom, R.

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AU - Fijten, M.W.M.

AU - Schubert, U.S.

PY - 2005

Y1 - 2005

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AB - The monomer concentration for the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide was optimized utilizing high-throughput experimentation methods. Detailed 1H-NMR spectroscopic investigations were performed to understand the mechanistic aspects of the observed concentration effects. Finally, the improved polymerization concentration was applied for the synthesis of higher molecular weight (> 10,000 Da) poly(2-ethyl-2-oxazoline)s.

U2 - 10.1002/pola.20603

DO - 10.1002/pola.20603

M3 - Article

SN - 0887-624X

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JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 7

ER -

Concentration effects in the cationic ring-opening polymerization of 2-ethyl-2-oxazoline in N,N-dimethylacetamide

Abstract

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