Comparing Environmental Impacts of Single-Junction Silicon and Silicon/Perovskite Tandem Photovoltaics: A Prospective Life Cycle Assessment

Tandem photovoltaics applying perovskite on silicon are considered to be a possible route to sustaining continuous efficiency improvements and price reductions. A meaningful market share for such tandems is, however, at least a decade away. Herein, a comprehensive prospective life cycle assessment was conducted, comparing the full life cycle of monofacial and bifacial silicon/perovskite tandem panels with single-junction silicon panels produced up to 2050. The end-of-life included the recovery of silicon and silver. Climate change impacts per kilowatt hour were projected to decrease by two-thirds over time. Tandem panels are expected to reach impacts of 8-10 g CO₂-eq/kWh in 2050, while single-junction panels may reach 11-13 g CO₂-eq/kWh in 2050. Other midpoint impact categories with substantial contributions to damaging human health and ecosystem quality were toxicity, particulate matter formation, and acidification, with tandems having lower impacts in each category. Reductions in impacts over time are mainly the result of grid mix decarbonization and panel efficiency improvements. Balance-of-system and recycling were found to contribute substantially to these impact categories. To ensure that tandem panels provide environmental benefits, annual degradation rates should not exceed 1% for monofacial or 3% for bifacial tandems, and refurbishment of panels with advanced degradation is crucial.