Commensurate freezing of n-Alkanes in silicalite

W.J.M. van Well; J.P. Wolthuizen; B. Smit; J.H.C. Hooff, van; R.A. Santen, van

doi:10.1002/anie.199525431

Commensurate freezing of n-Alkanes in silicalite

W.J.M. van Well
, J.P. Wolthuizen
, B. Smit
, J.H.C. Hooff, van
, R.A. Santen, van

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.

Original language	English
Pages (from-to)	2543-2544
Number of pages	2
Journal	Angewandte Chemie - International Edition
Volume	34
Issue number	22
DOIs	https://doi.org/10.1002/anie.199525431
Publication status	Published - 1995

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title = "Commensurate freezing of n-Alkanes in silicalite",

abstract = "Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.",

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year = "1995",

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language = "English",

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T1 - Commensurate freezing of n-Alkanes in silicalite

AU - van Well, W.J.M.

AU - Wolthuizen, J.P.

AU - Smit, B.

AU - Hooff, van, J.H.C.

AU - Santen, van, R.A.

PY - 1995

Y1 - 1995

N2 - Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.

AB - Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.

U2 - 10.1002/anie.199525431

DO - 10.1002/anie.199525431

M3 - Article

SN - 1433-7851

VL - 34

SP - 2543

EP - 2544

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 22

ER -

Commensurate freezing of n-Alkanes in silicalite

Abstract

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