TY - JOUR
T1 - Cold and ultracold NH-NH collisions in magnetic fields
AU - Janssen, L.M.C.
AU - Zuchowski, P.S.
AU - van der Avoird, A.
AU - Groenenboom, G.C.
AU - Hutson, J.M.
PY - 2011/2/28
Y1 - 2011/2/28
N2 - Elastic and spin-changing inelastic collision cross sections are presented for cold and ultracold magnetically trapped NH. The cross sections are obtained from coupled-channel scattering calculations as a function of energy and magnetic field. We specifically investigate the influence of the intramolecular spin-spin, spin-rotation, and intermolecular magnetic dipole coupling on the collision dynamics. It is shown that N15H is a very suitable candidate for evaporative cooling experiments. The dominant trap-loss mechanism in the ultracold regime originates from the intermolecular dipolar coupling term. At higher energies and fields, intramolecular spin-spin coupling becomes increasingly important. Our qualitative results and conclusions are fairly independent of the exact form of the potential and of the size of the channel basis set.
AB - Elastic and spin-changing inelastic collision cross sections are presented for cold and ultracold magnetically trapped NH. The cross sections are obtained from coupled-channel scattering calculations as a function of energy and magnetic field. We specifically investigate the influence of the intramolecular spin-spin, spin-rotation, and intermolecular magnetic dipole coupling on the collision dynamics. It is shown that N15H is a very suitable candidate for evaporative cooling experiments. The dominant trap-loss mechanism in the ultracold regime originates from the intermolecular dipolar coupling term. At higher energies and fields, intramolecular spin-spin coupling becomes increasingly important. Our qualitative results and conclusions are fairly independent of the exact form of the potential and of the size of the channel basis set.
UR - http://www.scopus.com/inward/record.url?scp=79952135474&partnerID=8YFLogxK
U2 - 10.1103/PhysRevA.83.022713
DO - 10.1103/PhysRevA.83.022713
M3 - Article
AN - SCOPUS:79952135474
SN - 1050-2947
VL - 83
JO - Physical Review A: Atomic, Molecular and Optical Physics
JF - Physical Review A: Atomic, Molecular and Optical Physics
IS - 2
M1 - 022713
ER -