COK-16: A cation-exchanging metal-organic framework hybrid

Sneha R. Bajpe; Eric Breynaert; Ana Martin-Calvo; Danilo Mustafa; Sofia Calero; Christine E.A. Kirschhock; Johan A. Martens

doi:10.1002/cplu.201300080

COK-16: A cation-exchanging metal-organic framework hybrid

Sneha R. Bajpe, Eric Breynaert, Ana Martin-Calvo, Danilo Mustafa, Sofia Calero, Christine E.A. Kirschhock, Johan A. Martens

Research output: Contribution to journal › Article › Academic › peer-review

15 Citations (Scopus)

Abstract

X-ray spectroscopy: Substoichiometric encapsulation of polyoxometalate ions into a metal-organic framework results in a fully functional cation exchanger with accessible porosity. Cu²⁺ cations compensating the charge of [PW₁₂O₄₀]^3- in the as-synthesized material can be exchanged with cations such as Na⁺ and Eu³⁺. When exchanged with Eu³⁺, the material appears bright red under UV irradiation (see figure).

Original language	English
Pages (from-to)	402-406
Number of pages	5
Journal	ChemPlusChem
Volume	78
Issue number	5
DOIs	https://doi.org/10.1002/cplu.201300080
Publication status	Published - May 2013
Externally published	Yes

Keywords

EXAFS spectroscopy
ion exchange
luminescence
metal-organic frameworks
polyoxometalates

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10.1002/cplu.201300080

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title = "COK-16: A cation-exchanging metal-organic framework hybrid",

abstract = "X-ray spectroscopy: Substoichiometric encapsulation of polyoxometalate ions into a metal-organic framework results in a fully functional cation exchanger with accessible porosity. Cu2+ cations compensating the charge of [PW12O40]3- in the as-synthesized material can be exchanged with cations such as Na+ and Eu3+. When exchanged with Eu3+, the material appears bright red under UV irradiation (see figure).",

keywords = "EXAFS spectroscopy, ion exchange, luminescence, metal-organic frameworks, polyoxometalates",

author = "Bajpe, \{Sneha R.\} and Eric Breynaert and Ana Martin-Calvo and Danilo Mustafa and Sofia Calero and Kirschhock, \{Christine E.A.\} and Martens, \{Johan A.\}",

year = "2013",

month = may,

doi = "10.1002/cplu.201300080",

language = "English",

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T2 - A cation-exchanging metal-organic framework hybrid

AU - Bajpe, Sneha R.

AU - Breynaert, Eric

AU - Martin-Calvo, Ana

AU - Mustafa, Danilo

AU - Calero, Sofia

AU - Kirschhock, Christine E.A.

AU - Martens, Johan A.

PY - 2013/5

Y1 - 2013/5

N2 - X-ray spectroscopy: Substoichiometric encapsulation of polyoxometalate ions into a metal-organic framework results in a fully functional cation exchanger with accessible porosity. Cu2+ cations compensating the charge of [PW12O40]3- in the as-synthesized material can be exchanged with cations such as Na+ and Eu3+. When exchanged with Eu3+, the material appears bright red under UV irradiation (see figure).

AB - X-ray spectroscopy: Substoichiometric encapsulation of polyoxometalate ions into a metal-organic framework results in a fully functional cation exchanger with accessible porosity. Cu2+ cations compensating the charge of [PW12O40]3- in the as-synthesized material can be exchanged with cations such as Na+ and Eu3+. When exchanged with Eu3+, the material appears bright red under UV irradiation (see figure).

KW - EXAFS spectroscopy

KW - ion exchange

KW - luminescence

KW - metal-organic frameworks

KW - polyoxometalates

UR - https://www.scopus.com/pages/publications/84877766211

U2 - 10.1002/cplu.201300080

DO - 10.1002/cplu.201300080

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SP - 402

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JO - ChemPlusChem

JF - ChemPlusChem

IS - 5

ER -

COK-16: A cation-exchanging metal-organic framework hybrid

Abstract

Keywords

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