Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization

B. Happ, C. Friebe, A. Winter, M.D. Hager, U.S. Schubert

Research output: Contribution to journalArticleAcademicpeer-review

17 Citations (Scopus)

Abstract

The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.
Original languageEnglish
Pages (from-to)3433-3441
JournalEuropean Polymer Journal
Volume45
Issue number12
DOIs
Publication statusPublished - 2009

Fingerprint

Ruthenium
copolymerization
Polymethyl Methacrylate
Copolymerization
ruthenium
copolymers
fragmentation
Copolymers
polymerization
Polymerization
chemistry
Alkynes
Azides
Cycloaddition
Methacrylates
Size exclusion chromatography
Polydispersity
cycloaddition
alkynes
chromatography

Cite this

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title = "Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization",
abstract = "The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.",
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Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization. / Happ, B.; Friebe, C.; Winter, A.; Hager, M.D.; Schubert, U.S.

In: European Polymer Journal, Vol. 45, No. 12, 2009, p. 3433-3441.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization

AU - Happ, B.

AU - Friebe, C.

AU - Winter, A.

AU - Hager, M.D.

AU - Schubert, U.S.

PY - 2009

Y1 - 2009

N2 - The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.

AB - The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.

U2 - 10.1016/j.eurpolymj.2009.09.010

DO - 10.1016/j.eurpolymj.2009.09.010

M3 - Article

VL - 45

SP - 3433

EP - 3441

JO - European Polymer Journal

JF - European Polymer Journal

SN - 0014-3057

IS - 12

ER -