Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization

B. Happ; C. Friebe; A. Winter; M.D. Hager; U.S. Schubert

doi:10.1016/j.eurpolymj.2009.09.010

Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization

B. Happ, C. Friebe, A. Winter, M.D. Hager, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

18 Citations (Scopus)

Abstract

The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.

Original language	English
Pages (from-to)	3433-3441
Journal	European Polymer Journal
Volume	45
Issue number	12
DOIs	https://doi.org/10.1016/j.eurpolymj.2009.09.010
Publication status	Published - 2009

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10.1016/j.eurpolymj.2009.09.010

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title = "Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization",

abstract = "The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.",

author = "B. Happ and C. Friebe and A. Winter and M.D. Hager and U.S. Schubert",

year = "2009",

doi = "10.1016/j.eurpolymj.2009.09.010",

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T1 - Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization

AU - Happ, B.

AU - Friebe, C.

AU - Winter, A.

AU - Hager, M.D.

AU - Schubert, U.S.

PY - 2009

Y1 - 2009

N2 - The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.

AB - The copper(I)-catalyzed azide-alkyne cycloaddition provided an easy and efficient access to a functionalized heteroleptic ruthenium(II) complex monomer. A grafted copolymer with the heteroleptic ruthenium(II) complex and methyl methacrylate (MMA) as comonomer was synthesized by reversible addition fragmentation chain transfer (RAFT) polymerization. The product was characterized by means of 1H NMR spectroscopy, UV/vis spectroscopy and size exclusion chromatography coupled with a photodiode array detector. The RAFT process itself led to a grafted copolymer with a low polydispersity index.

U2 - 10.1016/j.eurpolymj.2009.09.010

DO - 10.1016/j.eurpolymj.2009.09.010

M3 - Article

SN - 0014-3057

VL - 45

SP - 3433

EP - 3441

JO - European Polymer Journal

JF - European Polymer Journal

IS - 12

ER -

Click chemistry meets polymerization: Controlled incorporation of an easily accessible ruthenium(II) complex into a PMMA backbone via RAFT copolymerization

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