Chromium-​catalyzed CO2-eEpoxide copolymerization

J. Gurnham; S. Gambarotta; I.V. Korobkov; L. Jasinska; R. Duchateau

doi:10.1021/om5005644

Chromium-catalyzed CO2-eEpoxide copolymerization

J. Gurnham
, S. Gambarotta
, I.V. Korobkov
, L. Jasinska
, R. Duchateau

Research output: Contribution to journal › Article › Academic › peer-review

18 Citations (Scopus)

238 Downloads (Pure)

Abstract

Iminopyrrole, aminopyrrole, and aminophosphine ligands were complexed with various chromium sources, producing eight complexes that were tested for their catalytic behavior toward epoxide–CO2 copolymerization. As elucidated by MALDI-TOF-MS, copolymerizations afforded polycarbonates and poly(ether-carbonates) exhibiting linear or cyclic topologies.

Original language	English
Pages (from-to)	4401-4409
Number of pages	9
Journal	Organometallics
Volume	33
Issue number	17
DOIs	https://doi.org/10.1021/om5005644
Publication status	Published - 2014

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title = "Chromium-catalyzed CO2-eEpoxide copolymerization",

abstract = "Iminopyrrole, aminopyrrole, and aminophosphine ligands were complexed with various chromium sources, producing eight complexes that were tested for their catalytic behavior toward epoxide–CO2 copolymerization. As elucidated by MALDI-TOF-MS, copolymerizations afforded polycarbonates and poly(ether-carbonates) exhibiting linear or cyclic topologies.",

author = "J. Gurnham and S. Gambarotta and I.V. Korobkov and L. Jasinska and R. Duchateau",

year = "2014",

doi = "10.1021/om5005644",

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T1 - Chromium-catalyzed CO2-eEpoxide copolymerization

AU - Gurnham, J.

AU - Gambarotta, S.

AU - Korobkov, I.V.

AU - Jasinska, L.

AU - Duchateau, R.

PY - 2014

Y1 - 2014

N2 - Iminopyrrole, aminopyrrole, and aminophosphine ligands were complexed with various chromium sources, producing eight complexes that were tested for their catalytic behavior toward epoxide–CO2 copolymerization. As elucidated by MALDI-TOF-MS, copolymerizations afforded polycarbonates and poly(ether-carbonates) exhibiting linear or cyclic topologies.

AB - Iminopyrrole, aminopyrrole, and aminophosphine ligands were complexed with various chromium sources, producing eight complexes that were tested for their catalytic behavior toward epoxide–CO2 copolymerization. As elucidated by MALDI-TOF-MS, copolymerizations afforded polycarbonates and poly(ether-carbonates) exhibiting linear or cyclic topologies.

U2 - 10.1021/om5005644

DO - 10.1021/om5005644

M3 - Article

SN - 0276-7333

VL - 33

SP - 4401

EP - 4409

JO - Organometallics

JF - Organometallics

IS - 17

ER -

Chromium-​catalyzed CO2-eEpoxide copolymerization

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Chromium-catalyzed CO2-eEpoxide copolymerization