Chirality of dendritic macromolecules

H.W.I. Peerlings; M.P. Struijk; E.W. Meijer

Chirality of dendritic macromolecules

H.W.I. Peerlings
, M.P. Struijk
, E.W. Meijer

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

Abstract

The intriguing combination of chirality with the highly sym. nature of dendrimers is investigated using chiral dendritic surfaces. Also the enantiomerically pure dendrimer 1 is synthesized from S-solketal and is fully characterized. The chirality of the dendritic structure stems from the difference in generation of the two Frechet-wedges as attached to the primary alcs. of glycerol. Both enantiomeric forms of 1 do not exhibit any optical activity in the 200-800 nm range and are therefore referred to as cryptochiral dendrimers. [on SciFinder (R)]

Original language	English
Title of host publication	Book of Abstracts, 212th ACS National Meeting, Orlando, FL, August 25-29
Place of Publication	Orlando, FL
Publisher	American Chemical Society
Pages	ORGN-311
Publication status	Published - 1996
Event	212th ACS National Meeting - Orlando, United States Duration: 25 Aug 1996 → 29 Aug 1996

Conference

Conference	212th ACS National Meeting
Country/Territory	United States
City	Orlando
Period	25/08/96 → 29/08/96

Cite this

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title = "Chirality of dendritic macromolecules",

abstract = "The intriguing combination of chirality with the highly sym. nature of dendrimers is investigated using chiral dendritic surfaces. Also the enantiomerically pure dendrimer 1 is synthesized from S-solketal and is fully characterized. The chirality of the dendritic structure stems from the difference in generation of the two Frechet-wedges as attached to the primary alcs. of glycerol. Both enantiomeric forms of 1 do not exhibit any optical activity in the 200-800 nm range and are therefore referred to as cryptochiral dendrimers. [on SciFinder (R)]",

author = "H.W.I. Peerlings and M.P. Struijk and E.W. Meijer",

year = "1996",

language = "English",

pages = "ORGN--311",

booktitle = "Book of Abstracts, 212th ACS National Meeting, Orlando, FL, August 25-29",

publisher = "American Chemical Society",

address = "United States",

note = "212th ACS National Meeting ; Conference date: 25-08-1996 Through 29-08-1996",

}

TY - GEN

T1 - Chirality of dendritic macromolecules

AU - Peerlings, H.W.I.

AU - Struijk, M.P.

AU - Meijer, E.W.

PY - 1996

Y1 - 1996

N2 - The intriguing combination of chirality with the highly sym. nature of dendrimers is investigated using chiral dendritic surfaces. Also the enantiomerically pure dendrimer 1 is synthesized from S-solketal and is fully characterized. The chirality of the dendritic structure stems from the difference in generation of the two Frechet-wedges as attached to the primary alcs. of glycerol. Both enantiomeric forms of 1 do not exhibit any optical activity in the 200-800 nm range and are therefore referred to as cryptochiral dendrimers. [on SciFinder (R)]

AB - The intriguing combination of chirality with the highly sym. nature of dendrimers is investigated using chiral dendritic surfaces. Also the enantiomerically pure dendrimer 1 is synthesized from S-solketal and is fully characterized. The chirality of the dendritic structure stems from the difference in generation of the two Frechet-wedges as attached to the primary alcs. of glycerol. Both enantiomeric forms of 1 do not exhibit any optical activity in the 200-800 nm range and are therefore referred to as cryptochiral dendrimers. [on SciFinder (R)]

M3 - Conference contribution

SP - ORGN-311

BT - Book of Abstracts, 212th ACS National Meeting, Orlando, FL, August 25-29

PB - American Chemical Society

CY - Orlando, FL

T2 - 212th ACS National Meeting

Y2 - 25 August 1996 through 29 August 1996

ER -

Chirality of dendritic macromolecules

Abstract

Conference

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