Chirality of dendritic macromolecules

H.W.I. Peerlings, M.P. Struijk, E.W. Meijer

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademic

Abstract

The intriguing combination of chirality with the highly sym. nature of dendrimers is investigated using chiral dendritic surfaces. Also the enantiomerically pure dendrimer 1 is synthesized from S-solketal and is fully characterized. The chirality of the dendritic structure stems from the difference in generation of the two Frechet-wedges as attached to the primary alcs. of glycerol. Both enantiomeric forms of 1 do not exhibit any optical activity in the 200-800 nm range and are therefore referred to as cryptochiral dendrimers. [on SciFinder (R)]
Original languageEnglish
Title of host publicationBook of Abstracts, 212th ACS National Meeting, Orlando, FL, August 25-29
Place of PublicationOrlando, FL
PublisherAmerican Chemical Society
PagesORGN-311
Publication statusPublished - 1996
Event212th ACS National Meeting - Orlando, United States
Duration: 25 Aug 199629 Aug 1996

Conference

Conference212th ACS National Meeting
CountryUnited States
CityOrlando
Period25/08/9629/08/96

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