Chirality due to oxygen-18 substitution. Synthesis and chiroptical properties of (1S)-2,4-adamantanedione-4-18O

E.W. Meijer, H. Wynberg

Research output: Contribution to journalArticleAcademicpeer-review

8 Citations (Scopus)
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Abstract

Optically active (1S)-2,4-adamantanedione-4-18O (I) was prepd. by the route for chiral adamantanones. The 18O label is introduced in the final step by thermal decompn. of the 1,2-dioxetane-18O, prepd. by irradiating an enol ether in an atm. of 18O. The CD spectrum of I shows several bands of large amplitude. [on SciFinder (R)]
Original languageEnglish
Pages (from-to)1145-1146
JournalJournal of the American Chemical Society
Volume104
Issue number4
DOIs
Publication statusPublished - 1982

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