Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

K. Bert; T. Noël; W. Kimpe; J. Goeman; J. Van der Eycken

doi:10.1039/C2OB25871D

Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

K. Bert, T. Noël, W. Kimpe, J. Goeman, J. Van der Eycken

Micro Flow Chemistry and Synthetic Meth.

Research output: Contribution to journal › Article › Academic › peer-review

17 Citations (Scopus)

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Abstract

A small library of chiral imidate-ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee’s up to 100%).

Original language	English
Pages (from-to)	8539-8550
Journal	Organic & Biomolecular Chemistry
Volume	10
DOIs	https://doi.org/10.1039/C2OB25871D
Publication status	Published - 2012

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abstract = "A small library of chiral imidate-ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee{\textquoteright}s up to 100%).",

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Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. / Bert, K.; Noël, T.; Kimpe, W.; Goeman, J.; Van der Eycken, J.

In: Organic & Biomolecular Chemistry, Vol. 10, 2012, p. 8539-8550.

Research output: Contribution to journal › Article › Academic › peer-review

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T1 - Chiral imidate-ferrocenylphosphanes: synthesis and application as P,N ligands in iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins

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AU - Goeman, J.

AU - Van der Eycken, J.

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AB - A small library of chiral imidate-ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee’s up to 100%).

U2 - 10.1039/C2OB25871D

DO - 10.1039/C2OB25871D

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