Chemoenzymatic synthesis of branched polymers

J.W. Peeters; A.R.A. Palmans; E.W. Meijer; C.E. Koning; A. Heise

doi:10.1002/marc.200500011

Chemoenzymatic synthesis of branched polymers

J.W. Peeters
, A.R.A. Palmans
, E.W. Meijer
, C.E. Koning
, A. Heise

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

44 Citations (Scopus)

Abstract

The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymatic procedure by using 2-hydroxyethyl -bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP).

Original language	English
Pages (from-to)	684-689
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	26
Issue number	9
DOIs	https://doi.org/10.1002/marc.200500011
Publication status	Published - 2005

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10.1002/marc.200500011

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title = "Chemoenzymatic synthesis of branched polymers",

abstract = "The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymatic procedure by using 2-hydroxyethyl -bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP).",

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AU - Peeters, J.W.

AU - Palmans, A.R.A.

AU - Meijer, E.W.

AU - Koning, C.E.

AU - Heise, A.

PY - 2005

Y1 - 2005

N2 - The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymatic procedure by using 2-hydroxyethyl -bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP).

AB - The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymatic procedure by using 2-hydroxyethyl -bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP).

U2 - 10.1002/marc.200500011

DO - 10.1002/marc.200500011

M3 - Article

SN - 1022-1336

VL - 26

SP - 684

EP - 689

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 9

ER -

Chemoenzymatic synthesis of branched polymers

Abstract

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