Charged-species profiles in electronegative radio-frequency plasmas

D. Vender, W.W. Stoffels, E. Stoffels - Adamowicz, G.M.W. Kroesen, F.J. Hoog, de

Research output: Contribution to journalArticleAcademicpeer-review

64 Citations (Scopus)
1 Downloads (Pure)


The negative ion density profile in a low pressure oxygen rf plasma has been measured by a photodetachment technique. At an rf power of 10 W and a neutral pressure of 10 mTorr, a parabolic negative ion density profile is obtained with a peak density of 8×(10)*15 m-3 and a maximum ratio of negative ion to electron densities n-/ne¿18. Under these conditions, the most abundant positive ion, determined by ion mass spectrometry, is O2+ with O+ being less than 10% of the positive ion density. The most abundant negative ion is O- with O2- and O3- being less than 20% of the total negative charge density. The maximum in the density profile of negative ions shifts closer to the powered rf electrode as the pressure is increased in the asymmetric system. Comparison of the results to theory indicates that the asymmetry follows from an enhancement of the ionization rate near the powered electrode sheath. The parabolic profile is also obtained in CCl2F2 at low pressure. Simulations and measurements show a rapid drop in ion density near the sheath that may be related to the recently discussed ‘‘stratification’’ phenomenon in electronegative plasmas.
Original languageEnglish
Pages (from-to)2436-2444
Number of pages9
JournalPhysical Review E: Statistical, Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Issue number3
Publication statusPublished - 1995


Dive into the research topics of 'Charged-species profiles in electronegative radio-frequency plasmas'. Together they form a unique fingerprint.

Cite this