Charge transfer reactions of tris(dimethylamino)phosphine : solvent effects and ESR measurements

G. Boekestein, H.M. Buck

Research output: Contribution to journalArticleAcademicpeer-review

4 Citations (Scopus)

Abstract

It is demonstrated that the course of the reaction of tris(dimethylamino)phosphine with aromatic bromides is strongly dependent on the nature of the solvent. The reaction in DMF or THF gave rise to the formation of radicals, which could be measured directly or by the method of spin-trapping, using 2-methyl-2-nitrosopropane as a scavenger.
Original languageEnglish
Pages (from-to)1095-1101
JournalRecueil des Travaux Chimiques des Pays-Bas
Volume92
Issue number10
DOIs
Publication statusPublished - 1973

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