Ceiling temperature and low-temperature polymerization

D. Heikens; H. Geelen

doi:10.1016/0032-3861(62)90107-6

Ceiling temperature and low-temperature polymerization

D. Heikens, H. Geelen

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Abstract

The possibility of polymerizing monomers in different phys. states is discussed in terms of the different temp. gradients of the Gibbs free energies of liquid monomer, cryst. monomer, and polymer. The coiling temp., below which polymerization is feasible, depends on the phys. state of the monomer. Crystn. generally minimizes the possibility of polymerization. Spontaneous mixing of polymer and liquid monomer, because of the free energy of mixing, leads to the replacement of the coiling temp. by specific temps. for definite monomer/polymer compns. [on SciFinder (R)]

Original language	English
Pages (from-to)	591-594
Number of pages	4
Journal	Polymer
Volume	3
DOIs	https://doi.org/10.1016/0032-3861(62)90107-6
Publication status	Published - 1962

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@article{08c38d8fabfe426ab0379611bfec64c7,

title = "Ceiling temperature and low-temperature polymerization",

abstract = "The possibility of polymerizing monomers in different phys. states is discussed in terms of the different temp. gradients of the Gibbs free energies of liquid monomer, cryst. monomer, and polymer. The coiling temp., below which polymerization is feasible, depends on the phys. state of the monomer. Crystn. generally minimizes the possibility of polymerization. Spontaneous mixing of polymer and liquid monomer, because of the free energy of mixing, leads to the replacement of the coiling temp. by specific temps. for definite monomer/polymer compns. [on SciFinder (R)]",

author = "D. Heikens and H. Geelen",

year = "1962",

doi = "10.1016/0032-3861(62)90107-6",

language = "English",

volume = "3",

pages = "591--594",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Ceiling temperature and low-temperature polymerization

AU - Heikens, D.

AU - Geelen, H.

PY - 1962

Y1 - 1962

N2 - The possibility of polymerizing monomers in different phys. states is discussed in terms of the different temp. gradients of the Gibbs free energies of liquid monomer, cryst. monomer, and polymer. The coiling temp., below which polymerization is feasible, depends on the phys. state of the monomer. Crystn. generally minimizes the possibility of polymerization. Spontaneous mixing of polymer and liquid monomer, because of the free energy of mixing, leads to the replacement of the coiling temp. by specific temps. for definite monomer/polymer compns. [on SciFinder (R)]

AB - The possibility of polymerizing monomers in different phys. states is discussed in terms of the different temp. gradients of the Gibbs free energies of liquid monomer, cryst. monomer, and polymer. The coiling temp., below which polymerization is feasible, depends on the phys. state of the monomer. Crystn. generally minimizes the possibility of polymerization. Spontaneous mixing of polymer and liquid monomer, because of the free energy of mixing, leads to the replacement of the coiling temp. by specific temps. for definite monomer/polymer compns. [on SciFinder (R)]

U2 - 10.1016/0032-3861(62)90107-6

DO - 10.1016/0032-3861(62)90107-6

M3 - Article

SN - 0032-3861

VL - 3

SP - 591

EP - 594

JO - Polymer

JF - Polymer

ER -

Ceiling temperature and low-temperature polymerization

Abstract

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