Cation-assisted lattice improvement of highly siliceous ZSM-5 upon prolonged heat treatment

B. Kraushaar; J.W. Haan, de; L.J.M. Ven, van de; J.H.C. Hooff, van

doi:10.1246/cl.1986.1523

Cation-assisted lattice improvement of highly siliceous ZSM-5 upon prolonged heat treatment

B. Kraushaar, J.W. Haan, de, L.J.M. Ven, van de, J.H.C. Hooff, van

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Abstract

Prolonged heat treatment of highly siliceous, template-free ZSM-5 containing Na+ or K+ causes improvement of the lattice structure, migration of alkaline ions to the outer layers of the zeolite particles as shown by XPS and an increased isolation of = Si–ONa sites from = Si–OH sites, as shown by 29Si CP MAS NMR analyses of silylated products

Original language	English
Pages (from-to)	1523-1526
Journal	Chemistry Letters
Volume	15
Issue number	9
DOIs	https://doi.org/10.1246/cl.1986.1523
Publication status	Published - 1986

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title = "Cation-assisted lattice improvement of highly siliceous ZSM-5 upon prolonged heat treatment",

abstract = "Prolonged heat treatment of highly siliceous, template-free ZSM-5 containing Na+ or K+ causes improvement of the lattice structure, migration of alkaline ions to the outer layers of the zeolite particles as shown by XPS and an increased isolation of = Si–ONa sites from = Si–OH sites, as shown by 29Si CP MAS NMR analyses of silylated products",

author = "B. Kraushaar and \{Haan, de\}, J.W. and \{Ven, van de\}, L.J.M. and \{Hooff, van\}, J.H.C.",

year = "1986",

doi = "10.1246/cl.1986.1523",

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journal = "Chemistry Letters",

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T1 - Cation-assisted lattice improvement of highly siliceous ZSM-5 upon prolonged heat treatment

AU - Kraushaar, B.

AU - Haan, de, J.W.

AU - Ven, van de, L.J.M.

AU - Hooff, van, J.H.C.

PY - 1986

Y1 - 1986

N2 - Prolonged heat treatment of highly siliceous, template-free ZSM-5 containing Na+ or K+ causes improvement of the lattice structure, migration of alkaline ions to the outer layers of the zeolite particles as shown by XPS and an increased isolation of = Si–ONa sites from = Si–OH sites, as shown by 29Si CP MAS NMR analyses of silylated products

AB - Prolonged heat treatment of highly siliceous, template-free ZSM-5 containing Na+ or K+ causes improvement of the lattice structure, migration of alkaline ions to the outer layers of the zeolite particles as shown by XPS and an increased isolation of = Si–ONa sites from = Si–OH sites, as shown by 29Si CP MAS NMR analyses of silylated products

U2 - 10.1246/cl.1986.1523

DO - 10.1246/cl.1986.1523

M3 - Article

SN - 0366-7022

VL - 15

SP - 1523

EP - 1526

JO - Chemistry Letters

JF - Chemistry Letters

IS - 9

ER -

Cation-assisted lattice improvement of highly siliceous ZSM-5 upon prolonged heat treatment

Abstract

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