Catalytic oxidative dehydrogenation of cyclohexene

R.A. Sheldon; J.M. Sobczak

doi:10.1016/0304-5102(91)80056-9

Catalytic oxidative dehydrogenation of cyclohexene

R.A. Sheldon, J.M. Sobczak

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).

Original language	English
Pages (from-to)	1-6
Number of pages	6
Journal	Journal of Molecular Catalysis
Volume	68
Issue number	1
DOIs	https://doi.org/10.1016/0304-5102(91)80056-9
Publication status	Published - 1991

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title = "Catalytic oxidative dehydrogenation of cyclohexene",

abstract = "Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).",

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AU - Sheldon, R.A.

AU - Sobczak, J.M.

PY - 1991

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N2 - Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).

AB - Oxidation of cyclohexene, in the presence of a palladium catalyst and anthraquinone-2-sulfonic acid, sodium salt (AMS) as cocatalyst, has been shown to yield selectively benzene. The oxidative dehydrogenation reaction proceeds in the liquid phase under atmospheric molecular oxygen pressure. Palladium dichloride and palladium on charcoal, combined with AMS, are the catalyst systems which show optimum conversion of cyclohexene (85–100%) and selectivity to benzene (92–100%).

U2 - 10.1016/0304-5102(91)80056-9

DO - 10.1016/0304-5102(91)80056-9

M3 - Article

SN - 0304-5102

VL - 68

SP - 1

EP - 6

JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 1

ER -

Catalytic oxidative dehydrogenation of cyclohexene

Abstract

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