Catalytic oxidation of 1-butene over bismuth molybdate catalysts : I. The system Bi2O3-MoO3

A.C.A.M. Bleijenberg; B.C. Lippens; G.C.A. Schuit

doi:10.1016/0021-9517(65)90163-6

Catalytic oxidation of 1-butene over bismuth molybdate catalysts : I. The system Bi2O3-MoO3

A.C.A.M. Bleijenberg, B.C. Lippens, G.C.A. Schuit

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

In the system Bi2O3---MoO3 the following compounds were identified: 1. (1) Bi2O3 · 3MoO3 = Bi2(MoO4)3 m.p. 676 °C 2. (2) Bi2O3 · MoO3 = Bi2MoO6 = (BiO)2MoO4 m.p. 938 °C 3. (3) 3Bi2O3 · MoO3 = Bi6MoO12 m.p. 995 °C These compounds were found by investigation of the phase diagram of the Bi2O3---MoO3 binary system by means of thermal analysis. X-ray studies of sintered mixtures in this system confirmed the existence of the three compounds. A compound Bi2O3 · 2MoO3 could not be detected.

Original language	English
Pages (from-to)	581-585
Number of pages	5
Journal	Journal of Catalysis
Volume	4
Issue number	5
DOIs	https://doi.org/10.1016/0021-9517(65)90163-6
Publication status	Published - 1965

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@article{da93e2160bda4336ab59e084e724eea2,

title = "Catalytic oxidation of 1-butene over bismuth molybdate catalysts : I. The system Bi2O3-MoO3",

abstract = "In the system Bi2O3---MoO3 the following compounds were identified: 1. (1) Bi2O3 · 3MoO3 = Bi2(MoO4)3 m.p. 676 °C 2. (2) Bi2O3 · MoO3 = Bi2MoO6 = (BiO)2MoO4 m.p. 938 °C 3. (3) 3Bi2O3 · MoO3 = Bi6MoO12 m.p. 995 °C These compounds were found by investigation of the phase diagram of the Bi2O3---MoO3 binary system by means of thermal analysis. X-ray studies of sintered mixtures in this system confirmed the existence of the three compounds. A compound Bi2O3 · 2MoO3 could not be detected.",

author = "A.C.A.M. Bleijenberg and B.C. Lippens and G.C.A. Schuit",

year = "1965",

doi = "10.1016/0021-9517(65)90163-6",

language = "English",

volume = "4",

pages = "581--585",

journal = "Journal of Catalysis",

issn = "0021-9517",

publisher = "Academic Press Inc.",

number = "5",

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TY - JOUR

T1 - Catalytic oxidation of 1-butene over bismuth molybdate catalysts : I. The system Bi2O3-MoO3

AU - Bleijenberg, A.C.A.M.

AU - Lippens, B.C.

AU - Schuit, G.C.A.

PY - 1965

Y1 - 1965

N2 - In the system Bi2O3---MoO3 the following compounds were identified: 1. (1) Bi2O3 · 3MoO3 = Bi2(MoO4)3 m.p. 676 °C 2. (2) Bi2O3 · MoO3 = Bi2MoO6 = (BiO)2MoO4 m.p. 938 °C 3. (3) 3Bi2O3 · MoO3 = Bi6MoO12 m.p. 995 °C These compounds were found by investigation of the phase diagram of the Bi2O3---MoO3 binary system by means of thermal analysis. X-ray studies of sintered mixtures in this system confirmed the existence of the three compounds. A compound Bi2O3 · 2MoO3 could not be detected.

AB - In the system Bi2O3---MoO3 the following compounds were identified: 1. (1) Bi2O3 · 3MoO3 = Bi2(MoO4)3 m.p. 676 °C 2. (2) Bi2O3 · MoO3 = Bi2MoO6 = (BiO)2MoO4 m.p. 938 °C 3. (3) 3Bi2O3 · MoO3 = Bi6MoO12 m.p. 995 °C These compounds were found by investigation of the phase diagram of the Bi2O3---MoO3 binary system by means of thermal analysis. X-ray studies of sintered mixtures in this system confirmed the existence of the three compounds. A compound Bi2O3 · 2MoO3 could not be detected.

U2 - 10.1016/0021-9517(65)90163-6

DO - 10.1016/0021-9517(65)90163-6

M3 - Article

SN - 0021-9517

VL - 4

SP - 581

EP - 585

JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 5

ER -

Catalytic oxidation of 1-butene over bismuth molybdate catalysts : I. The system Bi2O3-MoO3

Abstract

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